Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 26, Pages 4312-4317Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201500765
Keywords
Chelates; Homogeneous catalysis; Hydrogenation; Ruthenium; Iridium
Categories
Funding
- European Union
- Synflow Consortium [NMP-2009-3.2-1, 246461]
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Straightforward preparation of five-membered P,N and P,O prochelates was easily achieved from 6-methyl-2-pyridinol and 2-quinolinol. From these ligands, access to the corresponding well-defined ruthenium(II) and iridium(III) complexes was investigated. Owing to the hemilability as well as the reversible proton-responsive character of these chelates, the resulting well-defined ruthenium complexes exhibit interesting activities in hydrogenation.
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