Journal
ACS CATALYSIS
Volume 7, Issue 3, Pages 2042-2046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b03621
Keywords
C- H amination; azodiformates; palladium-catalyzed; methylene; beta-amino acid derivatives
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Funding
- Thousand Youth Talents Plan, NSFC [21672145]
- Shanghai Jiao Tong University
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An efficient and convenient method enabling direct amination of unactivated methylene C(sp(3)) H bonds to form C-N bonds with azodiformates as amino source is described. This method highlights the emerging strategy of unactivated methylene as versatile functional groups in organic synthesis and provides a strategy to construct functionalized C-N bonds for the synthesis of complex molecules.
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