Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex

To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes

(2016) Kyung-Bin Cho et al.   CHEMICAL SOCIETY REVIEWS

A mononuclear nonheme cobalt(iii)–hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

(2016) Woon-Young Tcho et al.   DALTON TRANSACTIONS

Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes

(2016) Surin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-ray Spectroscopic Characterization of Co(IV) and Metal–Metal Interactions in Co4O4: Electronic Structure Contributions to the Formation of High-Valent States Relevant to the Oxygen Evolution Reaction

(2016) Ryan G. Hadt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mononuclear Nonheme High-Spin Iron(III)-Acylperoxo Complexes in Olefin Epoxidation and Alkane Hydroxylation Reactions

(2016) Bin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Balancing Act: Stability versus Reactivity of Mn(O) Complexes

(2015) Heather M. Neu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions

(2015) Bin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of high-valent cobalt-oxo phthalocyanine species in a cellulose matrix for eliminating organic pollutants

(2015) Nan Li et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Molecular Catalysts for Water Oxidation

(2015) James D. Blakemore et al.   CHEMICAL REVIEWS

The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

(2015) Zhuqi Chen et al.   CHEMICAL SOCIETY REVIEWS

How a [CoIV${^{\underline{.....}}}$O]2+Fragment Oxidizes Water: Involvement of a Biradicaloid [CoII-(⋅O⋅)]2+Species in Forming the OO Bond

(2015) Douglas W. Crandell et al.   ChemSusChem

Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation

(2015) Andy I. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water Oxidation by the [Co4O4(OAc)4(py)4]+ Cubium is Initiated by OH– Addition

(2015) Paul F. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

(2014) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions

(2014) Seungwoo Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

(2014) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

Progress in Base-Metal Water Oxidation Catalysis

(2014) Alexander Rene Parent et al.   ChemSusChem

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

(2014) Kallol Ray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst

(2014) Miao Zhang et al.   Nature Chemistry

Efficient C–H bond activations via O2cleavage by a dianionic cobalt(ii) complex

(2014) Andy I. Nguyen et al.   Chemical Science

Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

(2013) Seungwoo Hong et al.   DALTON TRANSACTIONS

Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11

(2013) Kallol Ray et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Sequential Oxidations of Thiolates and the Cobalt Metallocenter in a Synthetic Metallopeptide: Implications for the Biosynthesis of Nitrile Hydratase

(2013) Arnab Dutta et al.   INORGANIC CHEMISTRY

Reactive Intermediates in Cytochrome P450 Catalysis

(2013) Courtney M. Krest et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

The Artificial Leaf

(2012) Daniel G. Nocera   ACCOUNTS OF CHEMICAL RESEARCH

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The “Oxo Wall” Stands

(2012) Kevin P. O’Halloran et al.   INORGANIC CHEMISTRY

Assembly and Properties of Heterobimetallic CoII/III/CaII Complexes with Aquo and Hydroxo Ligands

(2012) David C. Lacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity

(2012) Dong Wang et al.   Chemical Science

The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

(2012) Johannes Hohenberger et al.   Nature Communications

The ORCA program system

(2011) Frank Neese   Wiley Interdisciplinary Reviews-Computational Molecular Science

An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions

(2010) Florian Felix Pfaff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

XAS and DFT Investigation of Mononuclear Cobalt(III) Peroxo Complexes: Electronic Control of the Geometric Structure in CoO2versus NiO2Systems

(2010) Ritimukta Sarangi et al.   INORGANIC CHEMISTRY

Synthesis, Structural, and Spectroscopic Characterization and Reactivities of Mononuclear Cobalt(III)−Peroxo Complexes

(2010) Jaeheung Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH

(2010) J. Gregory McAlpin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Cobalt–phosphate oxygen-evolving compound

(2008) Matthew W. Kanan et al.   CHEMICAL SOCIETY REVIEWS

Electronic Design Criteria for O−O Bond Formation via Metal−Oxo Complexes

(2008) Theodore A. Betley et al.   INORGANIC CHEMISTRY

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

(2008) Elena Poverenov et al.   NATURE

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+

(2008) M. W. Kanan et al.   SCIENCE