Exploring secondary-sphere interactions in Fe–NxHycomplexes relevant to N2fixation

Hydrogen Peroxide Coordination to Cobalt(II) Facilitated by Second-Sphere Hydrogen Bonding

(2016) Christian M. Wallen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes

(2016) Jonathan D. Egbert et al.   CHEMICAL COMMUNICATIONS

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

(2016) Peter J. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Model Calculations Suggest that the Central Carbon in the FeMo-Cofactor of Nitrogenase Becomes Protonated in the Process of Nitrogen Fixation

(2016) Per E. M. Siegbahn   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Fe-N2 Complex That Generates Hydrazine and Ammonia via Fe═NNH2: Demonstrating a Hybrid Distal-to-Alternating Pathway for N2 Reduction

(2016) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides

(2015) Shabnam Hematian et al.   ACCOUNTS OF CHEMICAL RESEARCH

Molecular Designs for Controlling the Local Environments around Metal Ions

(2015) Sarah A. Cook et al.   ACCOUNTS OF CHEMICAL RESEARCH

Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models

(2015) Cooper Citek et al.   ACCOUNTS OF CHEMICAL RESEARCH

Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities

(2015) Joan Serrano-Plana et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere

(2015) Thomas B. Rauchfuss   ACCOUNTS OF CHEMICAL RESEARCH

Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

(2015) Shinobu Itoh   ACCOUNTS OF CHEMICAL RESEARCH

Lessons from Nature: A Bio-Inspired Approach to Molecular Design

(2015) Sarah A. Cook et al.   BIOCHEMISTRY

Oxygen-evolving complex of Photosystem II: an analysis of second-shell residues and hydrogen-bonding networks

(2015) Leslie Vogt et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Beyond H2: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis

(2015) Cameron M Moore et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Electronic and Steric Influences of Pendant Amine Groups on the Protonation of Molybdenum Bis(dinitrogen) Complexes

(2015) Liezel A. Labios et al.   INORGANIC CHEMISTRY

Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3

(2015) John S. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural analysis of the coordination of dinitrogen to transition metal complexes

(2015) Benjamin Peigné et al.   Acta Crystallographica Section B-Structural Science Crystal Engineering and Materials

Arginine-Containing Ligands Enhance H2Oxidation Catalyst Performance

(2014) Arnab Dutta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

(2014) Nathaniel S. Sickerman et al.   CHEMICAL COMMUNICATIONS

Isolation of Iron(II) Aqua and Hydroxyl Complexes Featuring a Tripodal H-bond Donor and Acceptor Ligand

(2014) Ellen M. Matson et al.   INORGANIC CHEMISTRY

Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo

(2014) Ellen M. Matson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protonation Studies of a Tungsten Dinitrogen Complex Supported by a Diphosphine Ligand Containing a Pendant Amine

(2014) Charles J. Weiss et al.   ORGANOMETALLICS

Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase

(2014) T. Spatzal et al.   SCIENCE

N2Binding to the FeMo-Cofactor of Nitrogenase

(2014) Philipp P. Hallmen et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O2 Evolution

(2013) Emily Y. Tsui et al.   INORGANIC CHEMISTRY

Dinitrogen Reduction by a Chromium(0) Complex Supported by a 16-Membered Phosphorus Macrocycle

(2013) Michael T. Mock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex

(2013) Kazuki Umehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Transition Metal Lewis Acid/Base Triad System for Cooperative Substrate Binding

(2013) Oscar Tutusaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)

(2013) J. Rittle et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Recent advances in phenoxyl radical complexes of salen-type ligands as mixed-valent galactose oxidase models

(2012) Christopher T. Lyons et al.   COORDINATION CHEMISTRY REVIEWS

The controlled relay of multiple protons required at the active site of nitrogenase

(2012) Ian Dance   DALTON TRANSACTIONS

A Nitrogenase Cluster Model [Fe8S6O] with an Oxygen Unsymmetrically Bridging Two Proto-Fe4S3 Cubes: Relevancy to the Substrate Binding Mode of the FeMo Cofactor

(2012) Shun Ohta et al.   INORGANIC CHEMISTRY

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays

(2012) Colin T. Carver et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of Fe–NH2 to Fe–N2 with release of NH3

(2012) John S. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

(2011) Marc-Etienne Moret et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Generation by Hangman Metalloporphyrins

(2011) Chang Hoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elucidating the Role of the Proximal Cysteine Hydrogen-Bonding Network in Ferric Cytochrome P450cam and Corresponding Mutants Using Magnetic Circular Dichroism Spectroscopy

(2010) Mary Grace I. Galinato et al.   BIOCHEMISTRY

Progress in metallocarboxypeptidases and their small molecular weight inhibitors

(2010) Daniel Fernández et al.   BIOCHIMIE

Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes

(2010) Simone Friedle et al.   CHEMICAL SOCIETY REVIEWS

A role for nickel–iron cofactors in biological carbon monoxide and carbon dioxide utilization

(2010) Yan Kung et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation

(2010) Ryan L. Shook et al.   INORGANIC CHEMISTRY

Formation, Structure, and EPR Detection of a High Spin FeIV—Oxo Species Derived from Either an FeIII—Oxo or FeIII—OH Complex

(2010) David C. Lacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

(2009) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Hydrogen-Bond Facilitated Cycle for Oxygen Reduction by an Acid- and Base-Compatible Iron Platform

(2009) Han Sen Soo et al.   INORGANIC CHEMISTRY

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands

(2009) Matthew T. Whited et al.   INORGANIC CHEMISTRY

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS