Article
Chemistry, Inorganic & Nuclear
Inderpal Yadav, Ved Prakash, Mannar R. Maurya, Muniappan Sankar
Summary: Two new meso-substituted oxido-molybdenum corroles were synthesized and characterized. The thermogram showed excellent thermal stability of MoO[TTC] (1) up to 491 degrees C and good stability of MoO[TNPC] (2) up to 318 degrees C. The molybdenum(V) oxidation states were verified using EPR spectroscopy and exhibited axial compression with dxy1 configuration. The oxido-molybdenum(V) complexes demonstrated high catalytic activity and selectivity for epoxidation and bromination reactions, with MoO[TNPC] (2) showing better performance due to the presence of electron-withdrawing nitro groups.
INORGANIC CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Sushree Aradhana Patra, Monalisa Mohanty, Atanu Banerjee, Shivani Kesarwani, Felix Henkel, Hans Reuter, Rupam Dinda
Summary: Three ONNO donor tetradentate diamino bis(phenolato) salan ligands were synthesized and used to form vanadium complexes, which were characterized and evaluated through various analyses including structural determination, electrochemical behavior, protein interaction studies, and cytotoxicity assessments against cancer and normal cell lines. The cytotoxicity trend of the complexes correlates with their protein binding affinity.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Hiya Talukdar, Sandhya Rani Gogoi, Sazida Yasmin Sultana, Reshma Begum, Dikshita Dowerah, Bipul Sarma, Nashreen S. Islam
Summary: The present study synthesized new oxido and peroxidoniobium(V) complexes with biogenic ligands, maltol and deferiprone, and characterized them using various analytical and spectroscopic techniques. The complexes exhibited effective inhibition of the enzyme wheat thylakoid acid phosphatase and demonstrated good catalytic performance for styrene epoxidation under solventless conditions.
DALTON TRANSACTIONS
(2023)
Article
Crystallography
Heng-Qiang Zhang, Xia Juan, Xu Ning, Fu-Jian Fang, Xin Yang, Xiu-Jun Zheng
Summary: This is a report about the crystal structure of C3H10N3O5V. The crystal belongs to monoclinic system with cell parameters of a = 5.487(2) angstrom, b = 7.611(3) angstrom, c = 19.629(8) angstrom, β = 101.269(11) degrees. The cell volume is 803.9(5) angstrom(3).
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
(2022)
Article
Chemistry, Applied
Manas Sutradhar, Guilherme Marques, Mohamed M. A. Soliman, M. Fatima C. Guedes da Silva, Daniela S. S. Flores, Carlos M. Granadeiro, Salete S. Balula, Armando J. L. Pombeiro, Elisabete C. B. A. Alegria
Summary: In this study, two vanadium(V) complexes were synthesized and immobilized for the oxidation of toluene. The effects of various parameters on the reaction were investigated, and high product yields were achieved under optimized conditions.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Riya Ghosh, Snehasish Debnath, Arnab Bhattacharya, Debjani Pradhan, Pabitra B. Chatterjee
Summary: This study reports two mononuclear oxido-and dioxidovanadium(V) compounds 1 and 2 with an intramolecularly hydrogen bonded luminescent zwitterion ligand (HL). Both 1 and 2 are water soluble and fluorescent, and show highly selective instant response towards singlet oxygen and hypochlorite. The interaction between vanadium compounds and analytes were further studied using spectrofluorimetric titration, H-1 NMR, and theoretical calculations.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Chen Sun, Jennifer L. Jaimes, Alec H. Follmer, Joseph W. Ziller, Andrew S. Borovik
Summary: Non-heme Fe monooxygenases activate C-H bonds using intermediates with high-spin Fe-IV-oxido centers. A new tripodal ligand [pop](3-) was prepared to mimic these sites and stabilize metal centers in high oxidation states. The ligand was used to generate [Fe(IV)pop(O)](-), which showed reactivity with benzyl alcohol, suggesting the importance of hydrogen bonding interactions for reactivity.
Article
Chemistry, Inorganic & Nuclear
Atanu Banerjee, Sushree Aradhana Patra, Gurunath Sahu, Giuseppe Sciortino, Federico Pisanu, Eugenio Garribba, M. Fernanda N. N. Carvalho, Isabel Correia, Joao Costa Pessoa, Hans Reuter, Rupam Dinda
Summary: In this study, a series of mononuclear non-oxido vanadium(IV) complexes are synthesized and characterized. The complexes show distorted octahedral or trigonal prismatic arrangement around the metal center. The EPR and DFT data suggest the coexistence of different isomers in solution, and the ESI-MS results indicate partial oxidation of the complexes. The complexes exhibit moderate binding affinity towards bovine serum albumin and show cytotoxicity against cancer cells by inducing cell death through apoptosis.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Sascha T. Loeffler, Julian Huemmer, Andreas Scheurer, Frank W. Heinemann, Karsten Meyer
Summary: In this article, the synthesis and reactivity of a newly developed ligand precursor and its coordination chemistry with uranium were presented. The corresponding complexes were characterized by various spectroscopic and analytical techniques, providing insights into their molecular structures and properties.
Article
Engineering, Environmental
Youquan Zhang, Cheng Ma, Chunxiao Zhang, Li Ma, Shuai Zhang, Qun Huang, Chaoping Liang, Libao Chen, Liangjun Zhou, Weifeng Wei
Summary: A bidirectional catalyst, consisting of single vanadium (V) atoms with V-N4 coordination and vanadium nitride nanodots with nitrogen vacancies (VN1-x) on nitrogen-doped carbon nanosheets (VN1-x@V-NC), was designed to modify the separators for lithium-sulfur (Li-S) batteries. The modified separator showed improved catalytic activity for the formation and decomposition of Li2S, strong affinity towards soluble polysulfides, and stable long-term cycling performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Junhui Xiao, Nanlan Zhong, Kai Zou, Renju Cheng, Wenliang Xiong
Summary: In this study, a cleaner process of water leaching was proposed to extract vanadium from V-bearing roasted ore. The effects of various leaching parameters on vanadium recovery were investigated, as well as the vanadium leaching kinetics in the process. The results showed high efficiency with V2O5 leaching efficiency of 91.29% and decreased V2O5 content of leaching residue. The main findings revealed that diffusion and chemical reaction control vanadium's action mode in the water leaching process, in accordance with standard kinetic theory and experimental results.
Article
Chemistry, Multidisciplinary
Manas Sutradhar, Marta A. Andrade, Sonia A. C. Carabineiro, Luisa M. D. R. S. Martins, Maria de Fatima C. Guedes da Silva, Armando J. L. Pombeiro
Summary: In this study, oxidovanadium(V) and dioxidovanadium(V) compounds were synthesized and characterized, then immobilized on functionalized carbon materials for catalytic oxidation of cyclohexane. The immobilization of the catalysts on carbon materials improved the catalytic efficiency and enabled catalyst recyclability while maintaining good catalytic activity.
Article
Chemistry, Inorganic & Nuclear
Yao Chen, Xing Liu, Jian Zhou, Hua-hong Zou, Bin Xiang
Summary: Two new one-dimensional vanadium(III) chalcogenidostannates, incorporating [V(tepa)](3+) complexes as bridging groups, were achieved by solvothermal methods. These materials feature 1D sinusoidal chains and novel bridging modes of the [mu-Sn(2)Q(6)](4-) anion, with their magnetic, photocurrent response, and optical properties further studied.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Xiangyu Ren, Baokuan Chen, Gang Zhang, Yanfeng Bi, Lingling Dai, Guoping Yang
Summary: In this study, a new molybdovanadate cluster modified by bisphosphonate (BP) ligands was successfully synthesized, providing a new basic building unit for the preparation of polyoxometalates. By comparing the catalytic activity of the V-doped molybdovanadate cluster with other clusters without V=O in an organic model reaction, the significance of the V-replaced model containing V=O was confirmed.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Kyriakos Ioannou, Constantina Eleftheriou, Chryssoula Drouza, Kyriaki S. Pafiti, Tolis Panayi, Anastasios D. Keramidas, Lefteris C. Zacharia, Manos C. Vlasiou
Summary: Four novel mononuclear complexes of Zn2+ and V5+ ions were synthesized and characterized. The complexes demonstrated antibacterial and anticancer activities, with one of the complexes showing antioxidant activity.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Review
Chemistry, Multidisciplinary
Dawei Zhang, Tanya K. Ronson, You-Quan Zou, Jonathan R. Nitschke
Summary: Metal-organic cages, formed via coordination-driven self-assembly, show great promise as separation agents by selectively binding and distinguishing substances in solution through precise control of their structure. The use of cages as absorbents or incorporation into polymer membranes can enhance the efficiency and selectivity of separation processes. Challenges and potential future developments in using metal-organic cages for separations are also discussed.
NATURE REVIEWS CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Jun-Long Zhu, Dawei Zhang, Tanya K. Ronson, Wenjing Wang, Lin Xu, Hai-Bo Yang, Jonathan R. Nitschke
Summary: This study reports the self-assembly of a truxene-faced Zn4L4 tetrahedron capable of binding the smallest hydrocarbons in solution. By incorporating inward-facing ethyl groups, the cage cavity was tailored to encapsulate methane, ethane, and ethene via van der Waals interactions. Interestingly, gas capture showed divergent selectivities in solution and the amorphous solid state, which may have implications for designing new processes for methane and ethane purification.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
You-Quan Zou, Dawei Zhang, Tanya K. Ronson, Andrew Tarzia, Zifei Lu, Kim E. Jelfs, Jonathan R. Nitschke
Summary: This study demonstrates how the hydrogen-bonding ability of a BINOL-based dialdehyde subcomponent influences the stereochemical outcome of self-assembly. The presence of methyl groups alters the self-sorting behavior, while the axial chirality of the BINOL building block affects the handedness of the helicate metal center.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Marius Morgenroth, Mirko Scholz, Laure Guy, Kawon Oum, Thomas Lenzer
Summary: The excited-state dynamics of bridged and non-bridged chiral helicene-like bidibenzo[c,h]acridines deposited as a thin film were investigated. Photoexcitation at 370 nm populates the S-1 state, with internal conversion and intersystem crossing being the main decay pathways. Despite high excitation fluence, there were no indications for higher-order processes, and coherent acoustic phonons were observed in the films post photoexcitation.
Article
Chemistry, Multidisciplinary
Dawei Zhang, Quan Gan, Alex J. Plajer, Roy Lavendomme, Tanya K. Ronson, Zifei Lu, Jesper D. Jensen, Bo W. Laursen, Jonathan R. Nitschke
Summary: This study reports the construction of three structurally distinct self-assembled architectures formed from a single triazatriangulenium subcomponent A under different reaction conditions. The largest structure, pseudoicosahedral capsule 1, was formed at higher concentrations, while helicate 2 exclusively formed at lower concentrations. Conversion of pseudoicosahedron 1 or helicate 2 into tetrahedron 3 occurred following the addition of a CB11H12- or B12F122- template.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Marius Morgenroth, Mirko Scholz, Laure Guy, Kawon Oum, Thomas Lenzer
Summary: We have observed efficient induction of chirality in polyfluorene copolymer thin films by mixing with helicene-type chiral additives based on the dibenzo[c,h]acridine motif. Circular dichroism (CD) and circularly polarized luminescence (CPL) microscopy provide information about the chiral arrangements in the thin films. The CD signal shows a characteristic dependence on the film thickness, supporting a supramolecular origin of the strong chiral response.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Editorial Material
Chemistry, Medicinal
Laure Guy, Reiko Oda, Narcis Avarvari, Jeanne Crassous, Nina Berova, Gennaro Pescitelli, Oliver Trapp, Simona Collina
Editorial Material
Chemistry, Multidisciplinary
Dawei Zhang, Hai-Bo Yang
Summary: In this study, a new type of tetrahedral cage with each face spanned by three ligand panels was reported. The concept was achieved through self-assembly of a twisted tetramine subcomponent. The resulting structure has a large enclosed cavity that can accommodate multiple equivalents of large dianions.
Article
Chemistry, Multidisciplinary
Weichao Xue, Luca Pesce, Adinarayana Bellamkonda, Tanya K. Ronson, Kai Wu, Dawei Zhang, Nicolas Vanthuyne, Thierry Brotin, Alexandre Martinez, Giovanni M. Pavan, Jonathan R. Nitschke
Summary: This article reports on a tetrahedral FeII4L4 cage formed by the coordination of triangular chiral, face-capping ligands to iron(II). This cage exists as two diastereomers in solution, which differ in the stereochemistry of their metal vertices but share the same point chirality of the ligand. Guest binding subtly perturbs the equilibrium between these cage diastereomers, and atomistic well-tempered metadynamics simulations provide insight into the interplay between stereochemistry and fit. Understanding the stereochemical impact on guest binding enables the design of a straightforward process for the resolution of enantiomers.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Shuai-Liang Yang, Xiang Zhang, Qing Wang, Chao Wu, Haiming Liu, Dongmei Jiang, Roy Lavendomme, Dawei Zhang, En-Qing Gao
Summary: Confinement of discrete coordination cages within nanoporous lattices allows the regulation of their spin state through multilevel host-guest interactions. The confinement of an anionic Fe-II L-4(6) nanocage within the cationic framework of MIL-101 results in an ionic MOF with a hierarchical host-guest structure. The spin-crossover (SCO) behavior of Fe-II L-4(6)@MIL-101 can be induced by temperature and release/uptake of water guest, enabling highly selective colorimetric sensing of humidity.
Article
Biochemistry & Molecular Biology
Laure Guy, Maelle Mosser, Delphine Pitrat, Jean-Christophe Mulatier, Mercedes Kukulka, Monika Srebro-Hooper, Erwann Jeanneau, Amina Bensalah-Ledoux, Bruno Baguenard, Stephan Guy
Summary: A series of molecules with chiral connections between two quinolines, benzoquinolines, or phenanthrolines were developed, and their photophysical and chiroptical switching activity upon protonation was studied. The results showed significant changes in the spectral properties of these molecules in acidic medium, making them promising multifunctional pH probes.
Article
Materials Science, Multidisciplinary
Vivien Andrieux, Thomas Gibaud, Julien Bauland, Thibaut Divoux, Sebastien Manneville, Stephan Guy, Amina Bensalah-Ledoux, Laure Guy, Floris Chevallier, Denis Frath, Christophe Bucher
Summary: Redox-active conductive supramolecular gels involving highly ordered chiral assemblies of small organic molecules have been synthesized and characterized in this study. The gelation process and properties of the gels were thoroughly investigated, and it was found that the optical, rheological, and electrical properties of the gels can be tuned by adding ionic additives. The self-assembly process formed chiral hollow core-shell cylinders with specific dimensions.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Hoshang Sahib, Alban Gassenq, Amina Bensalah-Ledoux, Bruno Baguenard, Laure Guy, Stephan Guy
Summary: The polarization in photonic-integrated circuits (PICs) is controlled by the transverse electric (TE) and magnetic (TM) polarizations due to the planar structure of the chips. This study successfully demonstrates the realization of rib-channel chirowaveguides that support elliptically polarized guided modes by combining linear and circular birefringences.
ADVANCED PHOTONICS RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Marco Deiana, Maelle Mosser, Tangui Le Bahers, Elise Dumont, Marta Dudek, Sandrine Denis-Quanquin, Nasim Sabouri, Chantal Andraud, Katarzyna Matczyszyn, Cyrille Monnereau, Laure Guy
Summary: The study introduces a light-activated functional material capable of remotely controlling the formation of duplex and G-quadruplex nucleic acids at the cellular level, along with a novel extended heteroaromatic structure with remarkable binding properties. This work lays the groundwork for the future design and development of a new generation of light-activated target-selective G4-binders.
Article
Chemistry, Inorganic & Nuclear
Frederic Gendron, Sebastiano Di Pietro, Laura Abad Galan, Francois Riobe, Virginie Placide, Laure Guy, Francesco Zinna, Lorenzo Di Bari, Amina Bensalah-Ledoux, Yannick Guyot, Guillaume Pilet, Fabrice Pointillart, Bruno Baguenard, Stephan Guy, Olivier Cador, Olivier Maury, Boris Le Guennic
Summary: The electronic structure of a chiral Yb(iii)-based complex has been fully determined through a combination of experimental magnetic, luminescence, and chiroptical characterizations with ab initio wavefunction calculations. The high resolution electronic structure diagram and the nature of different states involved in the magnetic and chiroptical properties have been identified. Spectroscopic measurements were used to reproduce the magnetic properties, while advanced ab initio calculations revealed that global chiroptical spectra are a sum of entangled transitions with similar or opposite polarizations.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Alexander M. Prophet, Kritanjan Polley, Gary J. Van Berkel, David T. Limmer, Kevin R. Wilson
Summary: The oxidation kinetics of iodide by ozone at the air-water interface is studied in single microdroplets. Molecular simulations and kinetic modeling are used to understand the underlying multiphase mechanism.
Article
Chemistry, Multidisciplinary
Rong Zhang, Jiajing Lan, Fei Wang, Shumei Chen, Jian Zhang
Summary: By utilizing 1,1'-ferrocene dicarboxylic acid as a chelating and surface protection ligand, we have synthesized multi-nuclear indium oxide clusters with varying nuclear sizes, including heptanuclear and thirteen-nuclear clusters. These clusters possess labile coordination sites, allowing for structural modification and self-assembly, resulting in the formation of various cluster structures.
Article
Chemistry, Multidisciplinary
Hui Wang, Hui Liu, Mingsen Wang, Jiaheng Hou, Yongjun Li, Yuancheng Wang, Yingjie Zhao
Summary: Two supramolecular complexes were prepared using CBs and M1, and their single-crystal structures were analyzed by SCXRD. The unexpected 1:2 self-assembly structure between M1 and CB[8] was discovered for the first time. These complexes exhibit unique photophysical properties and provide valuable information about the structure and photophysical properties of supramolecular complexes.
Article
Chemistry, Multidisciplinary
Chang-Hee Lee, Sookil Park, Sanggil Kim, Ji Young Hyun, Hyun Soo Lee, Injae Shin
Summary: The epidermal growth factor receptor (EGFR) is a cell-surface glycoprotein involved in cell proliferation and tumor development. This study used a fluorescently labeled EGFR to investigate its time-dependent endocytosis in live cells and found that appended glycans affect EGFR internalization. Additionally, the study detected sialic acid residues attached to EGFR on the live cell surface using FRET-based imaging. This research provides valuable insights into the cellular functions of EGFR.
Article
Chemistry, Multidisciplinary
Subhankar Sahu, Lokesh Kumar, Sumita Das, Dipti Gupta, Ruchi Anand
Summary: This study proposes a strategy that combines organic electronics with biosensor scaffolds to create a compact device for monitoring environmental aromatic pollution. By coupling biosensing protein MopR with an organic electrochemical transistor (OECT), a sensor module capable of efficient detection of phenol was designed. Exclusive phenol detection with minimal loss of sensitivity could be achieved in complex pollutant mixtures and real environmental samples.
Review
Chemistry, Multidisciplinary
Changseok Lee, Hyung-Joon Kang, Sungwoo Hong
Summary: The formation of C-N bonds through hydroamination reactions catalyzed by nickel hydrides has been a topic of recent interest. This approach offers a way to efficiently transform a variety of alkene and alkyne substrates into compounds enriched with C-N bonds. The review provides a concise overview of the underlying reaction mechanisms and aims to stimulate further progress in NiH-catalytic techniques and catalyst design.
Article
Chemistry, Multidisciplinary
Yueci Wu, Lu-Lu Sun, Hai-Hao Han, Xiao-Peng He, Weiguo Cao, Tony D. James
Summary: Drug-induced liver injury (DILI) is a common cause of acute liver failure in the USA and Europe, but most cases can be recovered or prevented by discontinuing the offending drug. Recent research has found that peroxynitrite (ONOO-) can be used as a potential indicator for early diagnosis of DILI, and there is an urgent need to establish a method to detect and track peroxynitrite in DILI cases. In this study, a FRET-based nano fluorescent probe CD-N-I was developed, which showed high selectivity and sensitivity in detecting peroxynitrite. The probe successfully detected exogenous peroxynitrite in live cells and endogenous peroxynitrite in APAP-induced liver injury of HepG2 cells.
Article
Chemistry, Multidisciplinary
Dmitry L. Lipilin, Mikhail O. Zubkov, Mikhail D. Kosobokov, Alexander D. Dilman
Summary: This article describes a direct photocatalytic method for the thiolation of unprotected acids, which was previously challenging. By using a thionocarbonate reagent with an N-O bond, the efficient conversion of carboxylic acids to thiols is achieved.
Article
Chemistry, Multidisciplinary
Jason Malenfant, Lucille Kuster, Yohann Gagne, Kouassi Signo, Maxime Denis, Sylvain Canesi, Mathieu Frenette
Summary: Raman microscopy can reveal compound-specific vibrational fingerprints without sample preparation. The combination of efficient theoretical calculations and a user-friendly software can accurately predict peak positions and provide match scores to assist with structure determination.
Article
Chemistry, Multidisciplinary
Jayoh A. Hernandez, Paul S. Micus, Sean Alec Lois Sunga, Luca Mazzei, Stefano Ciurli, Gabriele Meloni
Summary: Essential trace metals play crucial roles in the survival and virulence of bacterial pathogens. Helicobacter pylori requires nickel for colonization and persistence in the stomach, and NixA is an essential nickel transporter in this process. This study characterizes the selectivity and electrogenic nature of NixA-mediated nickel transport.
Article
Chemistry, Multidisciplinary
Tarali Devi, Kuheli Dutta, Jennifer Deutscher, Stefan Mebs, Uwe Kuhlmann, Michael Haumann, Beatrice Cula, Holger Dau, Peter Hildebrandt, Kallol Ray
Summary: This study emphasizes the importance of subtle electronic changes and secondary interactions in the stability of biologically relevant metal-dioxygen intermediates. It also shows that the role of the chloride ligand in stabilizing the Fe-III-(OOBu)-Bu-t moiety can extend to other anions, including the thiolate ligand.
Article
Chemistry, Multidisciplinary
Jacqueline R. Santhouse, Jeremy M. G. Leung, Lillian T. Chong, W. Seth Horne
Summary: By studying the folding kinetics and mechanism of the BdpA sequence, researchers found that altering the backbone connectivity can affect protein folding. This suggests that protein mimetic chains have a significant degree of plasticity in transitioning between unfolded and folded states.
Article
Chemistry, Multidisciplinary
Divanshu Gupta, Ralf Einholz, Holger F. Bettinger
Summary: This study presents the first direct spectroscopic evidence of a cyclic seven-membered iminoborane. Compared to linear amino-iminoboranes, this cyclic iminoborane exhibits weakened bond strength and lower Lewis acidity value. The study suggests that the reduced ring strain of cyclic iminoborane prevents nitrogen fixation but allows facile (2 + 2) cycloaddition reaction with C2H4.
Article
Chemistry, Multidisciplinary
Renny Mathew, Aniruddha Mazumder, Praveen Kumar, Julie Matula, Sharmarke Mohamed, Petr Brazda, Mahesh Hariharan, Brijith Thomas
Summary: This study reveals the packing arrangement of partially disordered nitro-perylenediimide (NO2-PDI) using a synergistic approach that combines 3D ED, ssNMR, and DFT techniques. By overcoming these challenges, this methodology opens up new avenues for material characterization, driving exciting advancements in the field.
