Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN)2−

Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles

(2016) Wei Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Ambiphilic boron in 1,4,2,5-diazadiborinine

(2016) Baolin Wang et al.   Nature Communications

Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base

(2015) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt Boryl Complexes: Enabling and Exploiting Migratory Insertion in Base-Metal-Mediated Borylation

(2015) René Frank et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient access to the tricyanoborate dianion B(CN)32− and selected reactions as a boron-centred nucleophile

(2015) Johannes Landmann et al.   CHEMICAL COMMUNICATIONS

Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors

(2015) Lingbing Kong et al.   Chemical Science

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres

(2015) Di Wu et al.   Nature Communications

Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile

(2014) Lingbing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical

(2014) Rüdiger Bertermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heavy metal boryl chemistry: complexes of cadmium, mercury and lead

(2014) Andrey V. Protchenko et al.   CHEMICAL COMMUNICATIONS

An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]

(2014) David A. Ruiz et al.   CHEMICAL COMMUNICATIONS

Circumventing Redox Chemistry: Synthesis of Transition Metal Boryl Complexes from a Boryl Nucleophile by Decarbonylation

(2014) René Frank et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable GaX2, InX2 and TlX2 radicals

(2014) Andrey V. Protchenko et al.   Nature Chemistry

Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion

(2013) David A. Ruiz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organoaluminum Boryl Complexes

(2012) Nicole Dettenrieder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−

(2011) Eduard Bernhardt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion

(2010) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

(2010) Julien Monot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds

(2010) Andrey Solovyev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron−Metal Bonding Properties, and Application as a Polymerization Catalyst

(2009) Tomomi Terabayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Linear, Anionic Dimetalloborylene Complex

(2008) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments of Boryl Anions: Boron Analogues of Carbanion

(2008) Makoto Yamashita et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY