Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach

s-Block Metal Complexes with Bis- and Tris(pyrazolyl)methane and -methanide Ligands

(2016) Sven Krieck et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Experimental Basicities of Phosphazene, Guanidinophosphazene, and Proton Sponge Superbases in the Gas Phase and Solution

(2016) Ivari Kaljurand et al.   JOURNAL OF PHYSICAL CHEMISTRY A

“Inverse” Frustrated Lewis Pairs – Activation of Dihydrogen with Organosuperbases and Moderate to Weak Lewis Acids

(2016) Suresh Mummadi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tris(pyrazolyl)methanide Complexes of Trivalent Rare-Earth Metals

(2016) Tengfei Li et al.   ORGANOMETALLICS

Basicity Limits of Neutral Organic Superbases

(2015) Ivo Leito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tris(pyrazolyl)methanides of the Alkaline Earth Metals: Influence of the Substitution Pattern on Stability and Degradation

(2015) Christoph Müller et al.   INORGANIC CHEMISTRY

Synthesis, Structure, and Reactivity of Zwitterionic Divalent Rare-Earth Metal Silanides

(2015) Vidura D. Thalangamaarachchige et al.   INORGANIC CHEMISTRY

Tris(3,5-dimethylpyrazolyl)methane-Based Heterobimetallic Complexes that Contain Zn and CdTransition-Metal Bonds: Synthesis, Structures, and Quantum Chemical Calculations

(2014) Jens Meyer et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Extremely Bulky Tris(pyrazolyl)methanide: A Tridentate Ligand for the Synthesis of Heteroleptic Magnesium(II) and Ytterbium(II) Alkyl, Hydride, and Iodide Complexes

(2014) Ralte Lalrempuia et al.   Chemistry-An Asian Journal

Coinage Metal Complexes of Tris(pyrazolyl)methanide-Based Redox-Active Metalloligands

(2014) Sandra González-Gallardo et al.   ORGANOMETALLICS

Homoleptic Tetrakis(silyl) Complexes of Pd0and Pt0Featuring Metal-Centred Heterocubane Structures: Evidence for the Existence of the Corresponding Mononuclear PdIand PtIComplexes

(2013) Felix Armbruster et al.   CHEMISTRY-A EUROPEAN JOURNAL

Versatile Reactivity of a Lithium Tris(aryl)plumbate(II) Towards Organolanthanoid Compounds: Stable Lead-Lanthanoid-Metal Bonds or Redox Processes

(2013) Kornelia Zeckert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterobimetallic Cuprates Consisting of a Redox-Switchable, Silicon-Based Metalloligand: Synthesis, Structures, and Electronic Properties

(2013) Steffen Styra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound

(2013) Ahmed Al-Harbi et al.   DALTON TRANSACTIONS

A Zwitterionic Carbanion Frustrated by Boranes – Dihydrogen Cleavage with Weak Lewis Acids via an “Inverse” Frustrated Lewis Pair Approach

(2013) Hui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor–Acceptor Interactions

(2013) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridyl Compounds of Heavier Group 13 and 14 Elements as Ligands for Lanthanide Metals

(2013) Kornelia Zeckert   ORGANOMETALLICS

Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)

(2013) J. Rittle et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Main group pyridyl-based ligands; strategies to mixed metal complexes

(2012) Hayley R. Simmonds et al.   CHEMICAL COMMUNICATIONS

Dioxygen Reactivity of Biomimetic Iron-Catecholate and Iron-o-Aminophenolate Complexes of a Tris(2-pyridylthio)methanido Ligand: Aromatic CC Bond Cleavage of Catecholate versuso-Iminobenzosemiquinonate Radical Formation

(2012) Partha Halder et al.   CHEMISTRY-A EUROPEAN JOURNAL

Syntheses and structures of lanthanoid(ii) complexes featuring Sn–M (M = Al, Ga, In) bonds

(2012) Kornelia Zeckert   DALTON TRANSACTIONS

A Ru(I) Metalloradical That Catalyzes Nitrene Coupling to Azoarenes from Arylazides

(2012) Ayumi Takaoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc Catalysts for On-Demand Hydrogen Generation and Carbon Dioxide Functionalization

(2012) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Binding to Isostructural S = 1/2 and S = 0 Cobalt Complexes

(2012) Daniel L. M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of Zwitterionic Silylborates and Silylzincates with Pendant Polydonor Arms

(2012) Hui Li et al.   ORGANOMETALLICS

Investigations on the Steric Accessibility of the Carbanionic Moiety in Zwitterionic Magnesium Tris(pyrazolyl)methanide Complexes. Synthesis and Characterisation of Bi- and Tri­metallic Complexes

(2012) Jens Meyer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Structural characterization of zinc bicarbonate compounds relevant to the mechanism of action of carbonic anhydrase

(2012) Wesley Sattler et al.   Chemical Science

Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

(2011) Bryan Carlson et al.   CHEMICAL COMMUNICATIONS

Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2]

(2011) Daniel Kratzert et al.   CHEMICAL COMMUNICATIONS

A supramolecular approach to zwitterionic alkaline metal silanides and formation of heterobimetallic silanides

(2011) Hui Li et al.   CHEMICAL COMMUNICATIONS

Redox-Controlled, Reversible Rearrangement of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an “N,S-Confused” 2-Pyridylthiolate Arm

(2011) Naoto Kuwamura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Reactivity of New Pyrazolyl-Functionalized Potassium Silanides

(2011) Brian McNerney et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Homologous Series of Cobalt, Rhodium, and Iridium Metalloradicals

(2011) Ayumi Takaoka et al.   INORGANIC CHEMISTRY

Silylation of Iron-Bound Carbon Monoxide Affords a Terminal Fe Carbyne

(2011) Yunho Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Complexes of Sulfur-Ligated Iron

(2011) Ayumi Takaoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Mononuclear Organozinc Hydride Complex: Facile Insertion of CO2into a Zn–H Bond and CO2-Promoted Displacement of Siloxide Ligands

(2011) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Nonclassical Dihydrogen Adduct ofS=1/2Fe(I)

(2011) Yunho Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tin–lanthanoid donor–acceptor bonds

(2010) Kornelia Zeckert et al.   CHEMICAL COMMUNICATIONS

A triangulopalladium cluster consisting of μ3-capping silyl ligands

(2010) Felix Armbruster et al.   CHEMICAL COMMUNICATIONS

Carbene–carbanion equilibrium for tris(2-pyridylthio)methanido Fe(ii) complexes

(2010) Naoto Kuwamura et al.   DALTON TRANSACTIONS

Rearrangement of the Tris(2-pyridylthio)methanido Ligand in an Iron(II) Complex Containing an Fe−C Bond

(2010) Partha Halder et al.   INORGANIC CHEMISTRY

Catalytic N−N Coupling of Aryl Azides To Yield Azoarenes via Trigonal Bipyramid Iron−Nitrene Intermediates

(2010) Neal P. Mankad et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Four-Coordinate, Trigonal Pyramidal Pt(II) and Pd(II) Complexes

(2010) Charlene Tsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds

(2010) Michael G. Cushion et al.   ORGANOMETALLICS

Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands

(2009) Istemi Kuzu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lanthanide(II) Complexes of a Dual Functional Tris(2-pyridyl)stannate Derivative

(2009) Florian Reichart et al.   CHEMISTRY-A EUROPEAN JOURNAL

Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate κ1Si/κ3N-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand [Si(3,5-Me2pz)3]− (MeTpsd)

(2009) Felix Armbruster et al.   DALTON TRANSACTIONS

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands

(2009) Matthew T. Whited et al.   INORGANIC CHEMISTRY

E−H Bond Activation Reactions (E = H, C, Si, Ge) at Ruthenium: Terminal Phosphides, Silylenes, and Germylenes

(2009) Ayumi Takaoka et al.   ORGANOMETALLICS

Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn–C bond and DFT calculation of its one-electron oxidized species

(2008) Ken’ichi Kitano et al.   CHEMICAL COMMUNICATIONS

Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring “Free” Pyramidal Carbanions

(2008) Helen R. Bigmore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

The Multidentate Ligand (MeOMe2Si)3Si−: Unusual Coordination Modes in Alkali Metal Silanides

(2007) Clemens Krempner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION