Journal
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
Volume 97, Issue -, Pages 50-64Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2017.08.006
Keywords
Polyhedral oligomeric silsesquioxane; Hybrid monolithic column; Preparation method; Capillary liquid chromatography; Separation; Chromatographic application
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Funding
- National Natural Science Foundation of China [21675039]
- Young Talent of Hebei Province - China Postdoctoral Science Foundation [2016M591401]
- Young Talent Program in College and University of Hebei Province [BJ2014005]
- Hebei University Science Fund for Distinguished Young Scholars [2015JQ06]
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As a natural molecular-level organic-silica hybrid particle, polyhedral oligomeric silsesquioxane (POSS) is a good choice for the preparation of new hybrid monolithic columns because of its ease of fabrication, ultrahigh column efficiency, and excellent separation selectivity. In this review, we summarize the recently reported POSS-based hybrid monolithic columns, especially those reported in the recent 5 years. These POSS-based hybrid monolithic columns are classified according to the reactive groups of POSS and the introduced organically functionalized reagents, emphasizing the preparation methods and further applications in capillary liquid chromatography. (C) 2017 Elsevier B.V. All rights reserved.
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