Recent Advances in the Pauson–Khand Reaction

Total Synthesis of (−)-Nakadomarin A

(2016) J. Stephen Clark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Pauson–Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue

(2016) Thierry León et al.   CHEMICAL COMMUNICATIONS

Chiral diphosphine derivatives of alkylidyne tricobalt carbonyl clusters – A comparative study of different cobalt carbonyl (pre)catalysts for (asymmetric) intermolecular Pauson–Khand reactions

(2016) M. Abdul Mottalib et al.   POLYHEDRON

A 15-step synthesis of (+)-ryanodol

(2016) K. V. Chuang et al.   SCIENCE

Asymmetric Total Synthesis of Propindilactone G

(2015) Lin You et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Pauson–Khand Reaction Using a Small-Bite-Angle P-Stereogenic C1-Diphosphine Ligand

(2015) Edgar Cristóbal-Lecina et al.   ORGANOMETALLICS

Asymmetric Pauson–Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis

(2015) Takuma Furusawa et al.   TETRAHEDRON

MaxPHOS Ligand: PH/NH Tautomerism and Rhodium- Catalyzed Asymmetric Hydrogenations

(2014) Edgar Cristóbal-Lecina et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Allylation of Ketones and Subsequent Tandem Reactions Catalyzed by a Novel Polymer-Supported Titanium-BINOLate Complex

(2014) Jagjit Yadav et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselectivity of Intermolecular Pauson–Khand Reaction of Aliphatic Alkynes: Experimental and Theoretical Study of the Effect of Alkyne Polarization

(2014) Erika Fager-Jokela et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (+)-Ileabethoxazole via an Iron-Mediated Pauson–Khand [2 + 2 + 1] Carbocyclization

(2014) David R. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Concise Synthesis of (+)-Ingenol

(2014) Steven J. McKerrall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Intermolecular Cobalt-Catalyzed Pauson–Khand Reaction Using a P-Stereogenic Bis-phosphane

(2014) Sílvia Orgué et al.   ORGANIC LETTERS

Asymmetric Allylation/Pauson–Khand Reaction: A Simple Entry to Polycyclic Amines. Application to the Synthesis of Aminosteroid Analogues

(2014) Santos Fustero et al.   ORGANIC LETTERS

Synthesis and Application of β-Substituted Pauson-Khand Adducts: Trifluoromethyl as a Removable Steering Group

(2013) Nuria Aiguabella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Pauson–Khand reaction of medium sized trans-cycloalkenes

(2013) Agustí Lledó et al.   CHEMICAL COMMUNICATIONS

Development of an expedient intramolecular Pauson–Khand reaction approach to stereoselectively construct the trans-decalin with a C1 quaternary chiral center

(2013) Li-Li Shi et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Enyne Addition to Aldehydes and Rh(I)-Catalyzed Stereoselective Domino Pauson–Khand/[4 + 2] Cycloaddition

(2013) Wei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Total Synthesis of (+)-Fusarisetin A via the Intramolecular Pauson–Khand Reaction

(2013) Jun Huang et al.   ORGANIC LETTERS

Pauson–Khand Adducts of N-Boc-propargylamine: A New Approach to 4,5-Disubstituted Cyclopentenones

(2013) Nuria Aiguabella et al.   ORGANIC LETTERS

Asymmetric Intramolecular Pauson–Khand Reaction Mediated by a Remote Sulfenyl or Sulfinyl Group

(2012) José Luis García Ruano et al.   JOURNAL OF ORGANIC CHEMISTRY

Electronic Regioselectivity of Diarylalkynes in Cobalt-Mediated Pauson–Khand Reaction: An Experimental and Computational Study with Para- and Meta-Substituted Diarylalkynes and Norbornene

(2012) Erika Fager-Jokela et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Asymmetric Anti-Selective Michael Reactions of Aldehydes and the Sequential Reduction/Lactonization/Pauson–Khand Reaction for the Enantioselective Synthesis of Highly Functionalized Hydropentalenes

(2012) Bor-Cherng Hong et al.   ORGANIC LETTERS

Studies of iron-mediated Pauson–Khand reactions of 1,1-disubstituted-allenylsilanes: mechanistic implications for a reactive three-membered iron metallacycle

(2012) David R. Williams et al.   Chemical Science

Regiochemistry in Cobalt-Mediated Intermolecular Pauson–Khand Reactions of Unsymmetrical Internal Heteroaromatic Alkynes with Norbornene

(2011) Benjamin E. Moulton et al.   JOURNAL OF ORGANIC CHEMISTRY

Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson−Khand Reaction at Room Temperature

(2011) Mu-Hyun Baik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds

(2011) Mark Turlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Allenic Pauson–Khand Approach to 6,12-Guaianolides

(2011) Francois Grillet et al.   ORGANIC LETTERS

Pauson-Khand Reaction of Allenic Hydrocarbons: Synthesis of 4-Alkylidenecyclopentenones

(2010) Frédéric Antras et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Synthesis of Chiral Propargylic Alcohols for the Intramolecular Pauson−Khand Cycloaddition

(2010) Mark Turlington et al.   JOURNAL OF ORGANIC CHEMISTRY