Journal
TETRAHEDRON LETTERS
Volume 58, Issue 18, Pages 1755-1757Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.03.061
Keywords
Cross-cyclomagnesiation; 1,2-Dienes; Insect pheromones; Grignard reagents
Categories
Funding
- Russian Foundation for Basic Research [16-33-00378]
- RF [MD-6293.2016.3, NSh-6651.2016.3]
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The Ti-catalyzed intermolecular cross-cyclomagnesiation reaction of aliphatic and oxygenated 1,2-dienes with Grignard reagents was used as the key step to develop facile stereoselective methods for preparation of the major components of citrus leafminer moth (Phyllocnistis citrella) pheromones as well as cotton pink bollworm (Pectinophora gossypiella) and fruit fly (Drosophila melanogaster) attractants. (C) 2017 Elsevier Ltd. All rights reserved.
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