4.7 Article

Carbon dots and fluorescein: The ideal FRET pair for the fabrication of a precise and fully reversible ammonia sensor

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 253, Issue -, Pages 714-722

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2017.07.001

Keywords

Carbon dots; Ammonia sensor; Forster resonance energy transfer; Hydrophobic surfaces

Ask authors/readers for more resources

Monitoring of ammonia in the gas phase, a ubiquitous bulk chemical, is of paramount importance to ensure the safety of industrial workers. The present paper describes a solid-state optical ammonia sensor based on Forster resonance energy transfer (FRET) between narrowly dispersed blue-emitting carbon nanodots (CNDs) as FRET donor and fluorescein as FRET acceptor. The fluorophores were physically entrapped in a close to superhydrophobic sol-gel matrix, in turn deposited on a PVDF-HFP electrospun fiber membrane. The CNDs were synthesized via pyrolysis of ethylenediaminetetracetic acid (EDTA) in the presence of a hydrogen peroxide solution. X-ray photoelectron spectroscopy (XPS) confirmed a high surface coverage of hydrophilic groups, which is a result the addition of hydrogen peroxide in the reaction mixture. This translates into higher electrostatic interactions between ammonia and the fluorophores, in turn related to reduced FRET inter-distance between fluorescein and CNDs. If calibrated with respect to the fluorescein signal, the sensor shows a linear calibration with a remarkably low limit of detection, i.e. 110 ppb, and adequate reproducibility up to six N-2/NH3 cycles. (C) 2017 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Textiles

Characterization and modeling of thermal protective fabrics under Molotov cocktail exposure

Sumit Mandal, Guowen Song, Rene M. Rossi, Indu B. Grover

Summary: This study focused on characterizing and modeling thermal protective fabrics used in workwear under Molotov cocktail exposure. Significant fabric properties affecting the performance were identified, with thermal resistance and evaporative resistance found to negatively affect the transmitted thermal energy. The study concluded that the ANN model outperformed the MLR model in predicting protective performance.

JOURNAL OF INDUSTRIAL TEXTILES (2022)

Article Materials Science, Multidisciplinary

Conformal Integration of an Inkjet-Printed PbS QDs-Graphene IR Photodetector on a Polymer Optical Fiber

Goekhan Kara, Sami Bolat, Khushdeep Sharma, Matthias J. J. Grotevent, Dmitry N. N. Dirin, Dominik Bachmann, Roman Furrer, Luciano F. F. Boesel, Yaroslav E. E. Romanyuk, Rene M. Rossi, Maksym V. V. Kovalenko, Michel Calame, Ivan Shorubalko

Summary: This work successfully integrates an infrared photodetector with a polymer optical fiber, by wrapping graphene around the fiber and inkjet printing PbS quantum dots onto the curved surface. The resulting device acts as a functional coating and can detect infrared light without interrupting the waveguide. This cost-effective and adaptable hybrid detector approach brings us closer to multifunctional e-textiles and improved interfacing of the skin for wearable and non-invasive healthcare applications.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Article Nanoscience & Nanotechnology

Flexible, high-temperature-resistant silica-polymer aerogel hybrids by templating polymethylsilsesquioxane microstructure with trace polyimide

Xiaodong Wang, Ze Zhang, Yijun Wang, Wim J. Malfait, Shanyu Zhao, Yulin Tian, Ting Liu, Xiaoxue Zhang, Ai Du, Jun Shen

Summary: In this study, trace polyimide (PI) was used to modify the microstructure of polymethylsilsesquioxane (PMSQ) aerogel, resulting in a special neuronal network-like silica aerogel structure. The as-prepared PMSQ-PI hybrid aerogel exhibited dominated mesoporous structure, ultra-low thermal conductivity, super-hydrophobicity, high flexibility, excellent machinability, and high-temperature resistance. This new class of materials offers new perspectives for high-temperature-resistant insulators using strong silica-polymer hybrid aerogels.

ADVANCED COMPOSITES AND HYBRID MATERIALS (2023)

Article Chemistry, Multidisciplinary

Conductive Metal-Organic Frameworks with Tunable Dielectric Properties for Boosting Electromagnetic Wave Absorption

Xue Zhang, Xue-Lei Tian, Yutian Qin, Jing Qiao, Fei Pan, Na Wu, Changxian Wang, Shanyu Zhao, Wei Liu, Jie Cui, Zhao Qian, Meiting Zhao, Jiurong Liu, Zhihui Zeng

Summary: Metal-organic frameworks (MOFs) show potential in electromagnetic wave (EMW) absorption due to their tailored components, topological structure, and high porosity. In this study, rod-like conductive MOFs (cMOFs) composed of adjustable metal ions and ligands were prepared to achieve tunable dielectric properties for tailored EMW absorption. The influences of composition, charge transport, crystalline structure, and microstructure on dielectric and EMW absorption performance were investigated, advancing the understanding of EMW attenuation mechanisms. The cMOFs exhibited prominent EMW absorption due to enhanced conductive and polarization losses from conjugation effects, terminal groups, and shape anisotropy.

ACS NANO (2023)

Article Materials Science, Multidisciplinary

3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

Tingting Wu, Michal Ganobjak, Gilberto Siqueira, Zhihui Zeng, Mengmeng Li, Ekaterina Filimonova, Somayeh Saghamanesh, Anne Bonnin, Deeptanshu Sivaraman, Joshua Yip, Lei Li, Hui Wu, Gustav Nystrom, Wim J. Malfait, Shanyu Zhao

Summary: Aerogels were recognized as one of the top ten emerging technologies in chemistry by IUPAC in 2022. Their exceptional properties have led to the growth of the insulation market, but efforts are being made to explore their potential in other applications.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Review Health Care Sciences & Services

Advanced and Smart Textiles during and after the COVID-19 Pandemic: Issues, Challenges, and Innovations

Aleksandra Ivanoska-Dacikj, Yesim Oguz-Gouillart, Gaffar Hossain, Muslum Kaplan, Caglar Sivri, Jose Vicente Ros-Lis, Daiva Mikucioniene, Muhammad Usman Munir, Nuray Kizildag, Serkan Unal, Ivo Safarik, Esra Akgul, Nida Yildirim, Ayse Celik Bedeloglu, Omer Faruk Unsal, Gordon Herwig, Rene M. Rossi, Peter Wick, Pietro Clement, A. Sezai Sarac

Summary: The COVID-19 pandemic has had a significant impact on the textile and apparel industry. Despite the negative effects, such as supply chain disruptions and decreased demand, it has also accelerated the digitalization trend and the use of functional materials in the industry. This review paper focuses on the development of smart and advanced textiles in response to the outbreak of SARS-CoV-2, including monitoring and sensing capabilities through electrospun nanofibers and nanogenerators, as well as improved antiviral capabilities in medical textiles. The paper also highlights challenges in personal protective equipment disposal and provides an overview of new smart textile-based products for controlling and reducing the spread of SARS-CoV-2.

HEALTHCARE (2023)

Article Nanoscience & Nanotechnology

Sensing of KCl, NaCl, and Pyocyanin with a MOF-Decorated Electrospun Nitrocellulose Matrix

Lars Lueder, Peter Niraj Nirmalraj, Antonia Neels, Rene Michel Rossi, Michel Calame

Summary: Wearable sensors can provide important insight into a patient's health status by monitoring the concentration of specific biomarkers in body fluids. The integration of nanoporous metal-organic framework (MOF) particles with nitrocellulose (NC) fibrous layers using an electrospinning approach has been demonstrated, showing the efficiency of the MOF@NC structure as biosensors. The sensitivity and selectivity of this approach make it a promising platform for versatile and adaptable sensing of biomarkers.

ACS APPLIED NANO MATERIALS (2023)

Review Materials Science, Multidisciplinary

Aerogel-based solar-powered water production from atmosphere and ocean: A review

Jiaming Sun, Tingting Wu, Hui Wu, Wei Li, Lei Li, Shouxin Liu, Jing Wang, Wim J. Malfait, Shanyu Zhao

Summary: By imitating natural water circulation, artificial water generation processes can produce clean water by utilizing readily available and inexhaustible solar energy. Aerogels offer a great potential due to their three-dimensional, monolithic structure and porous, interconnected network. This paper reviews the material specifications and structural designs that aim to improve the evaporation performance, and discusses the challenges and future perspectives for the commercialization of aerogel-based water production systems.

MATERIALS SCIENCE & ENGINEERING R-REPORTS (2023)

Article Multidisciplinary Sciences

Surface-induced phase separation of reconstituted nascent integrin clusters on lipid membranes

Chiao-Peng Hsu, Jonas Aretz, Arsenii Hordeichyk, Reinhard Faessler, Andreas R. Bausch

Summary: Integrin adhesion complexes are crucial for cell membrane attachments, and the phase separation process can be enhanced by adding phosphoinositides to lipid membranes.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2023)

Article Materials Science, Textiles

Forced wetting of hydrophobic knitted fabrics analyzed with X-ray imaging

Florence Biguenet, Rolf Staempfli, Sascha Kruegl, Teo Georges, Dominique Dupuis, Rene M. Rossi, Marie-Ange Bueno

Summary: This study investigates the distribution of liquid in knitted fabrics using X-ray tomography, and finds that changes in hydrophobicity and porosity are the main factors affecting liquid distribution.

TEXTILE RESEARCH JOURNAL (2023)

Article Engineering, Biomedical

Development of a Textile Integrated, Two-State Controlled Tremor Suppression Orthosis for the Wrist

Nicolas P. Fromme, Adrian Esser, Martin Camenzind, Veit Mylius, Christian Baumann, Fabian Buechele, Robert Riener, Peter Wolf, Rene M. Rossi

Summary: This article introduces a new controlled energy dissipating suppression orthosis for the treatment of tremor. The orthosis has a decentralized suppression mechanism and integrated textiles, achieving tremor suppression rates of 78.8%, 66.5%, and 40.8% in simulations, test benches, and case studies, respectively, without any voluntary movement suppression.

IEEE TRANSACTIONS ON MEDICAL ROBOTICS AND BIONICS (2023)

Article Automation & Control Systems

FireDrone: Multi-Environment Thermally Agnostic Aerial Robot

David Hausermann, Sam Bodry, Fabian Wiesemuller, Aslan Miriyev, Severin Siegrist, Fan Fu, Sabyasachi Gaan, Matthias M. Koebel, Wim J. Malfait, Shanyu Zhao, Mirko Kovac

Summary: Deploying robots in extreme environments reduces risks to human lives, but environmental factors often limit robot operating conditions. This study presents a thermally agnostic aerial robot designed, modeled, and experimentally validated to overcome thermal challenges, inspired by natural thermal regulation principles. The robot incorporates structural thermally insulating material and a phase change material cooling system, allowing for operation in a broad range of ambient temperatures. The use of polyimide aerogel and silica aerogel particles enhances the robot's adaptability to extreme temperatures.

ADVANCED INTELLIGENT SYSTEMS (2023)

Article Chemistry, Multidisciplinary

Ibuprofen-loaded electrospun poly(ethylene-co-vinyl alcohol) nanofibers for wound dressing applications

Jean Schoeller, Karin Wuertz-Kozak, Stephen J. J. Ferguson, Markus Rottmar, Jonathan Avaro, Yvonne Elbs-Glatz, Michael Chung, Rene M. Rossi

Summary: The ability of poly(ethylene-co-vinyl alcohol) nanofibers to release ibuprofen for the treatment of chronic wounds was evaluated. The electrospinning of different compositions of poly(ethylene-co-vinyl alcohol) copolymers was optimized, and the release kinetics of ibuprofen from the nanofibers at different temperatures were studied. The scaffolds also showed no cytotoxicity to normal human fibroblasts, indicating their potential for use in chronic wound treatment.

NANOSCALE ADVANCES (2023)

Review Chemistry, Multidisciplinary

Visible light-responsive materials: the (photo)chemistry and applications of donor-acceptor Stenhouse adducts in polymer science

Michele Clerc, Sara Sandlass, Omar Rifaie-Graham, Julie A. Peterson, Nico Bruns, Javier Read de Alaniz, Luciano F. Boesel

Summary: Donor-acceptor Stenhouse adduct (DASA) photoswitches have attracted a lot of attention due to their negative photochromism, visible light absorbance, synthetic tunability, and large property changes. However, there are still challenges in understanding their behavior and incorporating them into polymers. This review summarizes the current understanding of DASA design and switching properties, discusses strategies of incorporating DASAs into polymers, and explores emerging applications of DASA photoswitches in polymeric materials.

CHEMICAL SOCIETY REVIEWS (2023)

Article Chemistry, Physical

Wicking fingering in electrospun membranes

Robert Fischer, Jean Schoeller, Rene M. Rossi, Dominique Derome, Jan Carmeliet

Summary: Pronounced fingering of the waterfront occurs during in-plane wicking in thin, aligned electrospun fibrous membranes. A non-local transport model considering the waterfront gradient and correlated random field is developed to explain this phenomenon. The size and shape of the fingers formed during wicking depend on the fiber orientation.

SOFT MATTER (2022)

Article Chemistry, Analytical

MEMS sensor based on MOF-derived WO3-C/In2O3 heterostructures for hydrogen detection

Mengmeng Guo, Na Luo, Yueling Bai, Zhenggang Xue, Qingmin Hu, Jiaqiang Xu

Summary: A porous heterostructure WO3-C/In2O3 was designed and prepared for a miniature H2 sensor, which showed higher response value, lower operating temperature, fast response-recovery speed, and low limit of detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Signal amplification strategy by chitosan-catechol hydrogel modified paper electrode for electrochemical detection of trace arsenite

Feng Hu, Hui Hu, Yuting Li, Xiaohui Wang, Xiaowen Shi

Summary: Arsenic contamination in water bodies is a significant health risk. This study developed a chitosan-catechol modified electrode for rapid and accurate detection of trace amounts of arsenic. The modified electrode demonstrated good detection capability and resistance to ionic interference, making it suitable for in situ detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A buffering fluorogenic probe for real-time lysosomal pH monitoring

Yantao Zhang, Qian Liu, Tao Tian, Chunhua Xu, Pengli Yang, Lianju Ma, Yi Hou, Hui Zhou, Yongjun Gan

Summary: In this study, a lysosome-targeting buffering fluorogenic probe (Lyso-BFP) was designed and synthesized, demonstrating excellent photostability, pH specificity, and responsiveness to lysosomal acidification in living cells. The performance of Lyso-BFP in pH sensing was attributed to the inhibition of the photo-induced electron transfer process. Lyso-BFP allowed for wash-free imaging and long-term real-time monitoring of lysosome pH changes based on its off-on fluorescence behavior and buffer strategy.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Rational design of α-glucosidase activated near-infrared fluorescent probe and its applications in diagnosis and treatment of diabetes

Wei Cai, Wenbo Sun, Jiayue Wang, Xiaokui Huo, Xudong Cao, Xiangge Tian, Xiaochi Ma, Lei Feng

Summary: In this study, a near-infrared fluorescent probe HCBG was developed for imaging of alpha-GLC. HCBG exhibited excellent selectivity and sensitivity towards alpha-GLC in complex bio-samples, and showed good cell permeability for in situ real-time imaging. Through the high-throughput screening system established by HCBG, a natural alpha-GLC inhibitor was successfully isolated and identified. This study provides a novel fluorescence visualization tool for discovering and exploring the biological functions of diabetes-related gut microbiota, and a high-throughput screening approach for alpha-GLC inhibitor.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Electrochemical immunosensor for the quantification of galectin-3 in saliva

Trey W. Pittman, Xi Zhang, Chamindie Punyadeera, Charles S. Henry

Summary: Heart failure is a growing epidemic and a significant clinical and public health problem. Researchers have developed a portable and affordable diagnostic device for heart failure that can be used at the point-of-care, providing a valid alternative to current diagnostics approaches.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Optical hydrogen peroxide sensor for measurements in flow

Anders O. Tjell, Barbara Jud, Roland Schaller-Ammann, Torsten Mayr

Summary: An optical hydrogen peroxide sensor based on catalytic degradation and the detection of produced oxygen is presented. The sensor offers higher resolution and better sensitivity at lower H2O2 concentrations. By removing O2 from the sample solution, a more sensitive O2 sensor can be used for measurement. The sensor has been successfully applied in a flow-through cell to measure H2O2 concentration in different flow rates.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Engineered vertically-aligned carbon nanotube microarray for self-concentrated SERS detection

Seong Jae Kim, Ji-hun Jeong, Gaabhin Ryu, Yoon Sick Eom, Sanha Kim

Summary: Surface-enhanced Raman spectroscopy (SERS) is a high-sensitivity, label-free detection method with various analytical applications. Researchers have developed a hydrophobic SERS substrate based on engineered carbon nanotube arrays (CNT-SERS) and studied the role of structural design at both micro and nanoscales. The substrate demonstrated controlled self-enrichment capability and enhanced sensitivity, with a significant increase in the SERS signal. The study also proposed a theoretical model and a concentration strategy inspired by plants for analyte deposition on microarrays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Flexible enzyme-like platform based on a 1-D CeVO4/2-D rGO-MCC heterostructure as sensor for the detection of intracellular superoxide anions

Dan Zhao, Renjun Jiang, Xiaoqiang Liu, Subbiah Alwarappan

Summary: In this study, a novel ternary composite material was constructed by assembling cerium vanadate nanorods on reduced graphene oxide-microcrystalline cellulose nanosheets, and it was used for real-time monitoring of the concentration of superoxide anions in vivo. The ternary composite showed excellent conductivity, large surface area, and abundant active sites, leading to a wider linear range, high sensitivity, low detection limit, and fast response time for superoxide anion detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Covalent organic framework enhanced aggregation-induced emission of berberine and the application for detection

Tengfei Wang, Liwen Wang, Guang Wu, Dating Tian

Summary: In this study, a covalent organic framework material TaTp-COF with porous and uniform spheres was successfully prepared via hydrothermal reaction, and it was found to significantly enhance the aggregation-induced emission (AIE) of berberine. The unique emission properties of berberine on TaTp-COF were studied and utilized for the sensitive detection of berberine.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Visualized time-temperature monitoring by triplet-sensitized ratiometric fluorescent nanosensors

Lin Li, Yilei Ding, Lei Xu, Shuoran Chen, Guoliang Dai, Pengju Han, Lixin Lu, Changqing Ye, Yanlin Song

Summary: In this study, a novel TTI based on a ratiometric fluorescent nanosensor is designed, which has the advantages of high accuracy and low cost. Experimental and theoretical investigations confirm its pH responsiveness and demonstrate its good sensitivity and reliability. By monitoring the total volatile basic nitrogen, this TTI can accurately predict food spoilage and can be adaptively modified for different types of food. The TTI based on this nanosensor enables visual monitoring of food quality.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A fluorescent prodrug to fight drug-resistant lung cancer cells via autophagy-driven ferroptosis

Fangju Chen, Xueting Wang, Wei Chen, Chenwen Shao, Yong Qian

Summary: Lung cancer is the second most common malignant tumor worldwide. Drug resistance in lung cancer leads to treatment failure and recurrence in majority of patients. This study developed a fluorescent prodrug that can be activated in cancer cells to release drugs, and its signal can be tracked by imaging. It shows a unique autophagy-driven ferroptosis effect, indicating its potential for targeting drug-resistant cancer cells.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

ZnO quantum dots sensitized ZnSnO3 for highly formaldehyde sensing at a low temperature

Weichao Li, Qiming Yuan, Zhangcheng Xia, Xiaoxue Ma, Lifang He, Ling Jin, Xiangfeng Chu, Kui Zhang

Summary: This study developed a high-performance gas sensor for formaldehyde detection by modifying ZnSnO3 with ZnO QDs and SnO2 QDs. The modified sensor showed improved sensing response and lower working temperature. The presence of ZnO QDs formed rich heterojunctions, increased surface area, and provided oxygen deficiency for formaldehyde sensing reaction, thus enhancing the sensor performance. This research provides an alternative method to enhance the sensing properties of MOS by QDs modification.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Development of highly sensitive plasmonic biosensors encoded with gold nanoparticles on M13 bacteriophage networks

Joung-Il Moon, Eun Jung Choi, Younju Joung, Jin-Woo Oh, Sang-Woo Joo, Jaebum Choo

Summary: A novel nanoplasmonic substrate was developed for biomedical applications, which showed strong hot spots for detecting biomarkers at low concentrations. The substrate, called AuNPs@M13, was made by immobilizing 60 nm gold nanoparticles onto the surface of an M13 bacteriophage scaffold. It demonstrated higher sensitivity and lower limit of detection compared to commercially available assays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Single-atom Cu-attached MOFs as peroxide-like enzymes to construct dual-mode immunosensors for detection of breast cancer typing in serum

Ning Li, Ya Zhang, Ying Xu, Xiaofang Liu, Jian Chen, Mei Yang, Changjun Hou, Danqun Huo

Summary: The molecular subtype of breast cancer guides treatment and drug selection. Invasive tests can promote cancer cell metastasis, so the development of high-performance, low-cost diagnostic tools for cancer prognosis is crucial. Liquid biopsy techniques enable noninvasive, real-time, dynamic, multicomponent, quantitative, and long-term observations at the cellular, genetic, and molecular levels. A Cu-Zr metal-organic framework (MOF) nanoenzyme with monatomic Cu attachment has been synthesized and proven to have high catalytic performance. The sensor constructed using this nanoenzyme shows potential for accurate classification of breast cancer serum samples.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Individually-addressable composite microneedle electrode array by mold-and-place method for glucose detection

Jeongmin Kim, Hyemin Kim, Seunghyun Park, Hyeonaug Hong, Yong Jae Kim, Jiyong Lee, Jaeho Kim, Seung-Woo Cho, Wonhyoung Ryu

Summary: This study presents a method to fabricate independently functioning microneedle (MN) electrodes with narrow intervals for high precision electrochemical sensing. The optimized mixture of photocurable polymer and single-wall carbon nanotubes was used to mold single composite MNs, which were then attached to pre-patterned electrodes. Plasma etching and electropolymerization were performed to enhance the electrochemical activity, and Prussian blue and glucose oxidase were electrodeposited on the MNs for glucose detection. The MN electrodes showed good sensitivity and linearity, and the feasibility of glucose detection was demonstrated in an in vivo mouse study.

SENSORS AND ACTUATORS B-CHEMICAL (2024)