Journal
SCIENCE CHINA-TECHNOLOGICAL SCIENCES
Volume 61, Issue 1, Pages 135-139Publisher
SCIENCE PRESS
DOI: 10.1007/s11431-017-9154-9
Keywords
surface structure; ceria; oxygen adatoms; oxygen vacancies; aberration-corrected TEM; first-principles calculations
Funding
- National Natural Science Foundation of China [51525102, 51390475, 51371102, 21673277]
- National Basic Research Program of China [2015CB654902]
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The behavior of oxygen on ceria surfaces is closely related with the applications of ceria as a catalyst and oxygen conductor in solid-oxide fuel cells. Here, the atomic configurations of oxygen adatoms and vacancies on the (110) surface of CeO2 have been studied combining aberration-corrected transmission electron microscopy and first-principles calculations. The oxygen adatoms were estimated to be located on top of Ce atoms with 50% coverage, forming a c(2x2) reconstruction. The oxygen vacancies can form stable configuration, with the Ce atoms partly reduced.
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