Article
Construction & Building Technology
Zixu Wang, David Shaw, Tara Kahan, Coralie Schoemaecker, Nicola Carslaw
Summary: This paper investigates the impacts of various factors on indoor photolysis rates and indoor air chemistry using a detailed chemical model. It found that glass type, artificial indoor lighting, cloudiness, time of year, and latitude all have significant effects on indoor photolysis rates and the production of potentially harmful species.
Article
Environmental Sciences
Luca Carena, Silvia Comis, Davide Vione
Summary: This study demonstrates the potential of using photochemical modeling to assess the photodegradation of agrochemicals in river water. The river Po was found to have particularly fast photodegradation kinetics due to agricultural nitrate inputs, making it a potentially vulnerable environment. The pesticide bentazon was identified as the safest among the studied pesticides, with fast degradation and low ecotoxicological impact of its transformation intermediates.
Article
Engineering, Chemical
Justyna Pamula, Magdalena Karnas, Anna Paluch, Katarzyna Styszko
Summary: This study evaluated the effectiveness of AOPs processes in degrading micropollutants in wastewater, finding that both the UV/H2O2 method and photocatalytic Fenton reaction were able to effectively remove pollutants, with optimized conditions achieving high removal rates.
DESALINATION AND WATER TREATMENT
(2022)
Article
Environmental Sciences
Yuanyuan Feng, Haiyan Du, Triana Wulandari, Gerrard Eddy Jai Poinern, Zhong-Tao Jiang, Derek Fawcett, Naveed Hassan, Lihong Xue, Linzhang Yang
Summary: This study investigates the effects and mechanisms of waste biomass-derived hydrochar on soil N2O effluxes. The results show that the enrichment of exogenous organics and nutrients at the hydrochar-soil interface enhances N2O fluxes.
Article
Engineering, Environmental
Mingxia Sun, Hongjie Song, Xiaobo Xie, Wenxi Yang, Yingying Su, Yi Lv
Summary: A specific luminescent probe was developed to selectively detect hydroxyl radicals, providing insights into the dynamic processes of hydroxyl radical generation and consumption.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Mingxue Li, Zexiu An, Yanru Huo, Jinchan Jiang, Yuxin Zhou, Haijie Cao, Zhehui Jin, Ju Xie, Jinhua Zhan, Maoxia He
Summary: In this study, the inhibitory effect of five omnipresent nitrogenous bases on the degradation of N-heterocyclic compounds under UV/peroxymonosulfate (PMS) was investigated using quantum chemical calculations. The study revealed the mechanisms and kinetics of self-inhibition and joint-degradation of N-heterocyclic compounds, which is significant for understanding the collective removal of contaminants in the real water environment.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Igor M. Piskarev
Summary: The study investigates the oxidation of substances in aqueous solutions using corona electric discharge to generate hydroxyl radicals. The experiments demonstrate the potential for reducing energy consumption by initiating and maintaining chain reactions, though inhibition of chain oxidative reactions of phenol was observed under certain conditions.
PLASMA CHEMISTRY AND PLASMA PROCESSING
(2021)
Article
Engineering, Environmental
Anna Wang, Zhechao Hua, Zihao Wu, Chunyan Chen, Shaodong Hou, Bangjie Huang, Yuge Wang, Ding Wang, Xuchun Li, Chuanhao Li, Jingyun Fang
Summary: This study examined the effects of bromide (Br-) at fresh water levels on radical chemistry in the UV/peroxydisulfate (UV/PDS) process. The presence of Br- promoted the conversion from sulfate radical (SO4-) to hydroxyl radical (HO-) and secondary reactive bromine species (RBS), significantly altering the radical chemistry of the process. Co-existing Cl- further enhanced the conversion from SO4- to HO- when combined with Br-.
Article
Engineering, Environmental
Emily Reidy, Brandon P. Bottorff, Colleen Marciel F. Rosales, Felipe J. Cardoso-Saldan, Caleb Arata, Shan Zhou, Chen Wang, Andrew Abeleira, Lea Hildebrandt Ruiz, Allen H. Goldstein, Atila Novoselac, Tara F. Kahan, Jonathan P. D. Abbatt, Marina E. Vance, Delphine K. Farmer, Philip S. Stevens
Summary: There have been relatively few measurements of the OH radical in indoor environments despite its importance outdoors. Elevated concentrations of OH were observed near a window during cooking events, in addition to elevated mixing ratios of HONO, VOCs, and NOX. The measured OH concentrations were underestimated by a chemical model, even during periods of direct sunlight, indicating incomplete understanding of oxidation in indoor environments.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Yadong Hu, Jianzhong Ma, Mengyu Zhu, Yijun Zhao, Shuchuan Peng, Chengzhu Zhu
Summary: The study on the photochemical reaction of o-dichlorobenzene in the presence of nitrite revealed that the degradation efficiency is influenced by the concentration of N(III), initial concentration of o-DCB, and pH value. The hydroxyl radicals generated by the photolysis of N(III) attack the benzene ring of o-DCB to form a new compound, leading to the formation of different products.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Chemistry, Physical
Chiao-Mi Cheng, Cheng-Zong Lu, Chun-Yao Hou, Yuan-Jyun Jhao, Yi-Fen Lai, I-Chia Chen, Yi-Hsueh Chuang, Li-Kang Chu
Summary: The photolytic products of nitrite and their oxidation effects on organic matter were studied in aqueous aerosols. In situ and real-time infrared and Raman spectroscopy revealed that nitrite and methanediol gradually decreased under 365 nm UVA irradiation, with the concomitant formation of nitrous oxide and formate, and eventually carbonate.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Engineering, Environmental
Dong Cheng, Yuansen Tan, Runhao Ma, Haoran Ding, Wenjuan Liao, Kai He, Rui Sun, Hengli Ni, Feng He
Summary: This study demonstrates the efficient degradation of nitrobenzene by FeS through a sequential reduction and oxidation process. Fe(II) and S(II) in FeS contribute electrons to the reduction of nitrobenzene. Addition of tripolyphosphate enhances the oxidation reaction, while TPP adsorption inhibits the surface oxidation reactivity of FeS. The effectiveness of FeS in degrading nitrobenzene in actual groundwater is demonstrated.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Pyeongeun Kim, Christian Boothby, Vicki H. Grassian, Robert E. Continetti
Summary: Energy transfer mechanisms initiated by light-absorbing organic molecules may play a significant role in the photochemistry of nitrate ions (NO3-) in water.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Jennifer S. Lewis, Adam P. Gaunt, Arnaud Comment
Summary: Despite more than 85 years of research, the mechanism behind the photodecarboxylation of pyruvic acid remains elusive. This study reveals that instead of decarboxylation, pyruvic acid acts as an electron donor and transfers an electron to an acceptor molecule, leading to degradation and the formation of CO2. The electron transfer occurs via hydrogen bonding, with the hydrated form of pyruvic acid acting as the electron acceptor.
Article
Engineering, Environmental
Carlos Dante Gamarra-Guere, Dawany Dionisio, Gessica Oliveira Santiago Santos, Marcos Roberto Vasconcelos Lanza, Artur de Jesus Motheo
Summary: Endocrine disruptors, such as MeP, are persistent pollutants in aquatic ecosystems. Among various advanced oxidation processes, electro-Fenton was found to be the most effective method for degrading MeP efficiently and quickly, outperforming other alternatives.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Public, Environmental & Occupational Health
Tarek Manasfi, Karine Lebaron, Maxime Verlande, Julien Dron, Carine Demelas, Laurent Vassalo, Gautier Revenko, Etienne Quivet, Jean-Luc Boudenne
INTERNATIONAL JOURNAL OF HYGIENE AND ENVIRONMENTAL HEALTH
(2019)
Article
Biochemical Research Methods
Rafal S. Strekowski, Coralie Alvarez, Jeanne Petrov-Stojanovic, Denis Hagebaum-Reignier, Henri Wortham
JOURNAL OF MASS SPECTROMETRY
(2019)
Article
Environmental Sciences
Tobias Sattler, Matthias Soergel, Julian Wittmer, Efstratios Bourtsoukidis, Torsten Krause, Elliot Atlas, Simon Benk, Sergej Bleicher, Katharina Kamilli, Johannes Ofner, Raimo Kopetzky, Andreas Held, Wolf-Ulrich Palm, Jonathan Williams, Cornelius Zetzsch, Heinz-Friedrich Schoeler
Article
Environmental Sciences
A. Figueiredo, R. S. Strekowski, L. Bosland, A. Durand, H. Wortham
SCIENCE OF THE TOTAL ENVIRONMENT
(2020)
Article
Environmental Sciences
Marion Hulin, Carole Leroux, Aurelie Mathieu, Aurelien Gouzy, Aurelie Berthet, Arnaud Boivin, Bernard Bonicelli, Catherine Chubilleau, Agnes Hulin, Eva Leoz Garziandia, Laure Mamy, Maurice Millet, Pierre Pernot, Etienne Quivet, Anne-Laure Scelo, Mathilde Merlo, Bernadette Ruelle, Carole Bedos
Summary: A method was developed to prioritize active substances for monitoring in ambient air in France, using a theoretical approach based on criteria such as national uses, emission potential, persistence, and toxicity. This led to the selection of 90 priority pesticides out of 1316 identified substances, with 43 requiring further development. The experts recommended a longer term monitoring of these substances after an exploratory campaign. The proposed method is reproducible, transparent, and adaptable to different agricultural and geographical conditions.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Biochemical Research Methods
Lea Ducup de Saint Paul, Sylvain Ravier, Henri Wortham, Francois Maupetit, Melanie Nicolas, Etienne Quivet
Summary: An analytical method using UPLC-MS/MS was developed and validated for the identification and quantification of seven isothiazolinones in consumer products, demonstrating high sensitivity. The method successfully detected and quantified all indicated isothiazolinones in various consumer products.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2021)
Article
Construction & Building Technology
Guillaume Karr, Etienne Quivet, Martine Ramel, Melanie Nicolas
Summary: The study found that noncombustible air fresheners may cause indoor air pollution and associated health risks, mainly influenced by volatile organic compounds, carbonyls, and fine particles. In worst-case usage scenarios, chronic exposure may exceed health reference standards. Reduction in emissions from high-emissivity products is necessary to decrease exposure levels.
Article
Engineering, Environmental
Etienne Quivet, Patrick Hohener, Brice Temime-Roussel, Julien Dron, Gautier Revenko, Maxime Verlande, Karine Lebaron, Carine Demelas, Laurent Vassalo, Jean-Luc Boudenne
Summary: Bromoform (CHBr3) is an important precursor of reactive bromine species in the troposphere and stratosphere. Previous models have only considered natural production of CHBr3 from marine organisms, but this study finds significantly higher levels of CHBr3 in water and air due to anthropogenic sources in an industrialized area. These findings suggest that industrial discharges may be an important missing factor in estimates of organic bromine flux to the atmosphere.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Florian Couvidat, Carole Bedos, Nathalie Gagnaire, Mathilde Carra, Bernadette Ruelle, Philippe Martin, Thomas Pomeon, Lionel Alletto, Alexandre Armengaud, Etienne Quivet
Summary: A module was implemented in the CHIMERE air quality model to simulate the volatilization of pesticides, allowing for the spatiotemporal distribution of pesticide atmospheric concentrations. The model was applied to S-metolachlor and folpet, with good performance in reproducing the spatial distribution of S-metolachlor concentrations but facing challenges in simulating folpet concentrations.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Review
Instruments & Instrumentation
Elena Gomez Alvarez, Nicola Carslaw, Sebastien Dusanter, Pete Edwards, Viktor Gabor Mihucz, Dwayne Heard, Joerg Kleffmann, Sascha Nehr, Coralie Schoemacker, Dean Venables
Summary: This paper reviews measurement techniques for radicals and their precursors in indoor air and provides considerations and pointers for indoor measurements. Recent advances in instrumental analysis and modeling studies have shown the need for a wider range of measurements for radical species and their precursors in indoor air, as well as techniques for determining actinic flux.
APPLIED SPECTROSCOPY REVIEWS
(2022)
Review
Instruments & Instrumentation
Milagros Rodenas Garcia, Andrea Spinazze, Pedro T. B. S. Branco, Francesca Borghi, Guillermo Villena, Andrea Cattaneo, Alessia Di Gilio, Victor G. Mihucz, Elena Gomez Alvarez, Sergio Ivan Lopes, Benjamin Bergmans, Cezary Orlowski, Kostas Karatzas, Goncalo Marques, John Saffell, Sofia I. V. Sousa
Summary: This article discusses the applications of low-cost sensors in indoor air quality monitoring, including their strengths and limitations. It provides recommendations for various indoor applications and discusses future trends.
APPLIED SPECTROSCOPY REVIEWS
(2022)
Review
Environmental Sciences
Dikaia E. Saraga, Xavier Querol, Regina M. B. O. Duarte, Noel J. Aquilina, Nuno Canha, Elena Gomez Alvarez, Milena Jovasevic-Stojanovic, Gabriel Beko, Steigvile Bycenkiene, Renata Kovacevic, Kristina Plauskaite, Nicola Carslaw
Summary: Source apportionment for indoor air pollution is challenging due to the complexity and variability of indoor sources, as well as the interconnectedness with the outdoor environment. This paper reviews the current understanding of source apportionment techniques, targeted pollutants, and identified sources, while highlighting limitations and knowledge gaps in this research field.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Chemistry, Analytical
Sean M. Power, Louis Free, Adrian Delgado, Chloe Richards, Elena Alvarez-Gomez, Ciprian Briciu-Burghina, Fiona Regan
Summary: This paper presents and evaluates a novel low-cost multi-spectral optical fluorometer, which uses LEDs and a mini-spectrometer to detect emitted fluorescence. The capabilities of the fluorometer are determined by testing known fluorophores. The application of the device for detecting chlorophyll a is demonstrated.
ANALYTICAL METHODS
(2023)
Article
Chemistry, Analytical
Sean M. Power, Louis Free, Adrian Delgado, Chloe Richards, Elena Alvarez-Gomez, Ciprian Briciu-Burghina, Fiona Regan
Summary: This paper presents and evaluates a novel low-cost multi-spectral optical fluorometer. The device uses LEDs in the blue and violet regions and a mini-spectrometer to detect emitted fluorescence in the UV to IR spectrum. Custom-built electronics and software control the system, housed in 3D printed parts. The capabilities of the fluorometer were tested using known fluorophores and compared to a benchtop fluorometer. The application of the device for chlorophyll a detection in laboratory-grown algae and environmental samples is demonstrated.
ANALYTICAL METHODS
(2023)
Article
Environmental Sciences
Enno Bahlmann, Frank Keppler, Julian Wittmer, Markus Greule, Heinz Friedrich Schoeler, Richard Seifert, Cornelius Zetzsch
ATMOSPHERIC CHEMISTRY AND PHYSICS
(2019)