Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 91, Issue 12, Pages 2310-2316Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602441711019X
Keywords
thulium orthophosphate; heat capacity; thermodynamic functions
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Funding
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences [0088-2014-0003]
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The heat capacity of TmPO4 in temperature ranges of 9.11-346.05 and 304.6-1344.6 K is measured via adiabatic and differential scanning calorimetry, respectively. The measurement data are used to calculate the temperature dependences of the heat capacity, entropy, change in enthalpy, and reduced Gibbs energy of TmPO4 in the range of 10-1344 K. The Gibbs energy of formation of thulium orthophosphate from elements Delta(f) G (0)(298.15 K) is determined.
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