Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 62, Issue 11, Pages 1479-1482Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023617110109
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Funding
- Russian Foundation for Basic Research [16-33-60182 mol_a_dk, 14-03-00864 A, 16-33-00714 mol_a]
- Council of the Russian Federation [MK-4654.2016.3]
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A single-stage scheme for the synthesis of carboxonium derivatives of the closo-decaborate anion by the reaction between the [B10H11](-) anion and carboxylic acids was proposed. Target compounds were separated and characterized by IR and H-1, B-11, C-13 NMR spectroscopy. In addition to the target compounds, closo-decaborate cluster opening products ere formed, and in the reaction between the closo-decaborate anion and acetic acid, a polymeric product was observed. The polymeric product (Ph4P) (n) [2,6,3,7-B10H6O2CCH3] (n) was characterized by X-ray diffraction.
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