Journal
RESEARCH ON CHEMICAL INTERMEDIATES
Volume 44, Issue 2, Pages 829-841Publisher
SPRINGER
DOI: 10.1007/s11164-017-3138-6
Keywords
Bimetallic oxides; Nitrogen-rich activated carbon; Carbonates; Carbon capture; Chemical adsorption
Categories
Funding
- Universiti Kebangsaan Malaysia [GUP-2016-056, DIP-2016-010]
Ask authors/readers for more resources
Mixed Cu and Mg oxides on nitrogen-rich activated carbon (AC) from Nypha fruticans biomass were characterized and their CO2 adsorption performance was measured. Highly dispersed CuO and MgO nanoparticles on AC was obtained using an ultrasonic-assisted impregnation method. The optimum adsorbent is 5%CuO-25%MgO/AC having good surface properties of high surface area, pores volume and low particles agglomeration. The higher content of MgO of 5%CuO-25%MgO/AC adsorbent contributes to less metal carbide formation which increases their porosity, surface area and surface basicity. XPS analysis showed some amount of nitrogen content on the surface of the adsorbent which increased their surface basicity towards selective CO2 adsorption. The presence of moisture accelerated the CO2 chemisorption to form a hydroxyl layer on the surfaces. The 5%CuO-25%MgO/AC adsorbent successfully adsorbed CO2 via physisorption and chemisorption of 14.8 and 36.2 wt%, respectively. It was significantly higher than fresh AC with better selectivity to CO2.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available