4.7 Article

Temporal-spatial distributions and ecological risks of perfluoroalkyl acids (PFAAs) in the surface water from the fifth-largest freshwater lake in China (Lake Chaohu)

Journal

ENVIRONMENTAL POLLUTION
Volume 200, Issue -, Pages 24-34

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2015.01.028

Keywords

Perfluoroalkyl acids; Residual levels; Temporal-spatial distributions; Fluorescent dissolved organic matter; Species sensitivity distribution model; Ecological risks; Lake Chaohu

Funding

  1. National Science Foundation of China (NSFC) [41030529, 41271462]
  2. National Project for Water Pollution Control [2012ZX07103-002]
  3. National Foundation for Distinguished Young Scholars [40725004]
  4. 111 Project [B14001]

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To investigate the residues, compositions, distributions and potential ecological risks of perfluoroalkyl acids (PFAAs), water samples were collected seasonally between August 2011 and November 2012 from 20 sites in Lake Chaohu and its tributary rivers. The mean concentration of total PFAAs (TPFAAs) was 14.46 +/- 6.84 ng/L PFOA was the predominant contaminant (8.62 +/- 4.40 ng/L), followed by PFBA (2.04 +/- 1.16 ng/L) and PFHxA (1.23 +/- 1.50 ng/L). The TPFAAs concentrations peaked in August 2012 in each area, except for the western river. The opposite spatial trends were found for PFOA and PFOS in both the lake and river areas. Except for PFOS and PFUdA, the levels of TPFAAs and PFAAs were significantly related to the composition of fluorescent dissolved organic matter (FDOM) but not related to total DOM expressed by dissolved organic carbon (DOC). The risk of PFOS determined by a species sensitivity distribution model was notably above that of PFOA. (C) 2015 Published by Elsevier Ltd.

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