4.7 Article

Persistent endosulfan sulfate is found with highest abundance among endosulfan I, II, and sulfate in German forest soils

Journal

ENVIRONMENTAL POLLUTION
Volume 206, Issue -, Pages 661-666

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2015.08.023

Keywords

Endosulfan; Stockholm-convention; Diffuse pollution; Soil monitoring; Forest soils

Funding

  1. environmental research fund of the federal minister of environment and nuclear safety/Germany [UFOPLAN FKZ 3707 71 201]

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Endosulfan - an agricultural insecticide and banned by Stockholm Convention - is produced as a 2:1 to 7:3 mixture of isomers endosulfan I (ESI) and endosulfan II (ESII). Endosulfan is transformed under aerobic conditions into endosulfan sulfate (ESS). The study shows for 76 sampling locations in German forests that endosulfan is abundant in all samples with an opposite ratio between the ESI and ESII than the technical product, where the main metabolite ESS is found with even higher abundance. The ratio between ESI/ESII and ESS show clear dependence on the type of stands (coniferous vs. deciduous) and humus type and increases from deciduous via mixed to coniferous forest stands. The study argues for a systematic monitoring of ESI, ESII, and ESS and underlines the need for further research, specifically on the fate of endosulfan including biomagnifications and bioaccumulation in soil. (C) 2015 Elsevier Ltd. All rights reserved.

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