Hydrodynamic and chemical effects of hydrogen addition on soot evolution in turbulent nonpremixed bluff body ethylene flames

The evolution of soot in a turbulent nonpremixed bluff body ethylene/hydrogen (2:1 by volume) flame was investigated using a combination of experiments and Large Eddy Simulations and compared with a neat ethylene counterpart (Muelleret al., 2013). The maximum soot volume fraction in the recirculation zone and jet-like region of the ethylene/hydrogen case are significantly lower than that of the ethylene case. Flamelet calculations demonstrated that hydrogen addition suppressed soot formation due to the reduction of the C/H ratio, resulting in an estimated fourfold reduction in soot volume fraction due to chemical effects. Soot reduction in the downstream jet-like region of the flame is quantitatively consistent with this chemical effect. However, soot reduction in the recirculation zone is substantially larger than this analysis suggests, indicating an additional hydrodynamic effect. Large Eddy Simulation was used to further investigate soot evolution in the recirculation zone and to elucidate the role of hydrogen addition. For the same heat release rate and similar jet Reynolds number as the neat ethylene case, the addition of hydrogen requires a higher jet velocity, and this leads to a leaner recirculation zone that inhibits soot formation and promotes soot oxidation. (C) 2016 by The Combustion Institute. Published by Elsevier Inc.