4.5 Article

Synergistic effect of hybrid graphene and boron nitride on the cure kinetics and thermal conductivity of epoxy adhesives

Journal

POLYMERS FOR ADVANCED TECHNOLOGIES
Volume 28, Issue 12, Pages 1851-1864

Publisher

WILEY
DOI: 10.1002/pat.4072

Keywords

graphene; guarded hot plate technique; non-isothermal; activation energy

Funding

  1. Board of Research in Nuclear Sciences-BRNS, Department of Atomic Energy (DAE), Government of India [39/11/2015-BRNS]

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In the present study, the synergistic effect of hybrid boron nitride (BN) with graphene on the thermal conductivity of epoxy adhesives has been reported. Graphene was prepared by chemical reduction of graphite oxide (GO) in a mixture of concentrated H2SO4/H3PO4 acid. The particle size distribution of GO was found to be similar to 10m and a low contact angle of 54 degrees with water indicated a hydrophilic surface. The structure of prepared graphene was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), Raman spectroscopy and atomic force microscopy (AFM). The thermal conductivity of adhesives was measured using guarded hot plate technique. Test results indicated an improvement in the thermal conductivity up to 1.65W/mK, which was about ninefold increase over pristine epoxy. Mechanical properties of different epoxy formulations were also measured employing lap shear test. The surface characterization of different epoxy adhesive systems was characterized through XRD, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies. Fourier transform infrared also served to determine the nature of interactions between filler particles and epoxy resin. Non-isothermal differential scanning calorimetric (DSC) technique was used to investigate the effects of graphene and BN particles on the cure kinetics and cross-linking reaction of epoxy cured with amine curing agent. The Kissinger equation, the model-free isoconversional Flynn-Wall-Ozawa method and the Ozawa model were used to analyze the kinetic parameter. Copyright (c) 2017 John Wiley & Sons, Ltd.

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