Article
Chemistry, Physical
Evgeniy G. Osadchii, Veniamin B. Polyakov, Valentin O. Osadchii
Summary: Silver telluride, AgTe3, was synthesized under high pressure and temperature conditions, with its crystal structure, thermodynamic properties, and virtual chemical reaction studied. Partial decomposition was observed during storage, and the standard Gibbs energy and thermodynamic properties of AgTe3 were determined for the first time using the electromotive force method.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Energy & Fuels
Mykola Moroz, Fiseha Tesfaye, Pavlo Demchenko, Myroslava Prokhorenko, Nataliya Yarema, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa
Summary: Equilibrium phase formations below 600 K in certain regions of the Fe-Ag-Ge-Te system were established using the electromotive force (EMF) method. Thermodynamic quantities of AgFeTe2, Ag2FeTe2, and Ag2FeGeTe4 were experimentally determined, confirming the reliability of the phase region division.
Article
Chemistry, Physical
Dandan Huang, Rumo Han, Yao Wang, Tianfan Ye
Summary: The Cu-Te binary system, particularly the Cu2Te superionic conductor, has attracted significant interest in thermoelectric applications. Experimental and thermodynamic modeling techniques were used to investigate phase equilibria, with 16 crucial alloys analyzed to confirm phase relations including polymorphic transitions in Cu2Te, Cu4Te3 and CuTe. A thermodynamic optimization was conducted, resulting in a set of self-consistent thermodynamic parameters that align well with experimental data.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Energy & Fuels
Mykola Moroz, Fiseha Tesfaye, Pavlo Demchenko, Emanuela Mastronardo, Oksana Mysina, Myroslava Prokhorenko, Serhiy Prokhorenko, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa
Summary: This study investigated the equilibrium concentration space of the Ag-In-Te system in the region of AgInTe2-Te-In2Te3 and identified the formation of stable phases in the different phase regions. The standard thermodynamic functions of binary and ternary compounds were determined using the solid-state electromotive force (EMF) method.
Article
Chemistry, Physical
M. Ilatovskaia, O. Fabrichnaya
Summary: Phase relations in the Al2O3-MnOx system were investigated, showing that Al2MnO4 melts by peritectic reaction at 2000 K. A new thermodynamic description of the Al-Mn-O system was derived using experimental data and thermodynamic parameters were evaluated to describe experimental data in the entire compositional range.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Sanghyeok Im, Shun-Li Shang, Nathan D. Smith, Adam M. Krajewski, Timothy Lichtenstein, Hui Sun, Brandon J. Bocklund, Zi-Kui Liu, Hojong Kim
Summary: Thermodynamic properties of the Nd-Bi system were investigated using a combination of experimental measurements, first-principles calculations, data mining and machine learning predictions, and calculation of phase diagrams. New peritectic reaction and crystal structure of NdBi2 were confirmed, and a more complete phase diagram of the Nd-Bi system was calculated based on newly acquired experimental data and DFT-based calculations.
Article
Materials Science, Ceramics
Tiantian Yin, Jaesung Lee, Elmira Moosavi-Khoonsari, In-Ho Jung
Summary: The thermodynamic properties and phase diagram data of the Sn-O system at 1 atm total pressure were evaluated and optimized to obtain a set of thermodynamic functions of stable phases. Discrepancies among experimental phase diagram data were resolved, and new experiments confirmed the high melting temperature of SnO2. A new phase diagram was constructed based on the optimized Gibbs energy functions of all phases.
CERAMICS INTERNATIONAL
(2021)
Article
Thermodynamics
Kevin J. Meisner, Rahim Zaman, Bi-Cheng Zhou
Summary: In this study, CALPHAD thermodynamic models of the Ta-O system were developed using experimental data and first-principles calculations. The models accurately represent the equilibrium polymorphs of Ta2O5 and the O solubility in BCC Ta. Preliminary models for the liquid Ta-O phase were also developed. The calculated phase diagrams are consistent with existing experimental data.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2022)
Article
Thermodynamics
Chenchen Dong, Jiong Wang, Biao Hu, Longpeng Zhu, Qing Wu, Yong Du
Summary: Thermodynamic descriptions of the tellurium-zirconium, tellurium-cerium, and tellurium-europium systems were conducted using the CALPHAD method based on experimental phase equilibrium data and first-principles calculations. The modeling successfully accounted for most reliable experimental information available in the literature.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
A. E. Seidzade, E. N. Orujlu, D. M. Babanly, S. Z. Imamaliyeva, M. B. Babanly
Summary: The SnTe-Sb2Te3-Te system was studied using X-ray powder diffraction and EMF measurements. A solid phase diagram was constructed and equations for temperature-dependent EMF were derived. The study investigated the behavior of SnTe in alloys and calculated the thermodynamic functions of tin in these alloys.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Gunel S. Hasanova, Aytan I. Aghazade, Samira Z. Imamaliyeva, Yusif A. Yusibov, Mahammad B. Babanly
Summary: The Bi-Te alloys were studied using various methods to determine phase diagrams, lattice parameters, and reactions. It was found that most compounds melt with decomposition reactions, except for Bi2Te3. EMF measurements were used to determine the partial molar functions of bismuth and standard thermodynamic functions of bismuth tellurides.
Article
Materials Science, Multidisciplinary
Sourav Kumar Panda, In-Ho Jung
Summary: Thermodynamic optimization of phase diagrams and properties were carried out for the FeO-Fe2O3-MnO-Mn2O3-TiO2-Ti2O3 system at 1 atm pressure. Experimental determination of isothermal phase diagrams and use of thermodynamic models led to reliable prediction of phase equilibria.
METALS AND MATERIALS INTERNATIONAL
(2021)
Article
Thermodynamics
Wenjie Wei, Weiwei Zhao, Gaoyang Liu, Zhanmin Cao
Summary: A thermodynamic description of the Ti-C-N-O quaternary system was achieved by evaluating the constituent ternary systems. These ternary systems were merged into a single database for predicting phase equilibria within the Ti-C-N-O quaternary system. Different phases were described using various thermodynamic models and the obtained model parameters reproduced the available phase diagram and thermodynamic data accurately.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2023)
Article
Thermodynamics
Lin Liao, Yanwen Liu, Shuhong Liu, Bo Jin, Yong Du
Summary: This study re-assessed the ternary Ag-Ni-Sn and constituent binary Ag-Sn and Ni-Sn systems using the CALPHAD method and improved the thermodynamic descriptions based on available experimental data. The updated thermodynamic parameters were found to be reliable and accurate through comprehensive comparisons with experimental data.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2022)
Article
Engineering, Chemical
Sinn-Wen Chen, Yi Chen, Jia -Ruei Chang, Hsin-jay Wu
Summary: This study investigates the interfacial reactions between Co and GeTe and determines the phase diagram of the Co-Ge-Te ternary system. It is found that Co reacts with GeTe to form multiple compounds at both 500 degrees C and 400 degrees C, with Co being the primary diffusion species in the Co/GeTe reaction couples. The results suggest that Co is not suitable as a barrier layer for GeTe at 500 degrees C.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Geochemistry & Geophysics
T. A. Stolyarova, M. V. Voronin, E. G. Osadchii, E. A. Brichkina
GEOCHEMISTRY INTERNATIONAL
(2015)
Article
Geochemistry & Geophysics
T. A. Stolyarova, M. V. Voronin, E. G. Osadchii, E. A. Brichkina
GEOCHEMISTRY INTERNATIONAL
(2015)
Article
Geochemistry & Geophysics
E. G. Osadchii, T. A. Stolyarova, M. V. Voronin, E. A. Brichkina
GEOCHEMISTRY INTERNATIONAL
(2017)
Article
Geochemistry & Geophysics
Valentin O. Osadchii, Mikhail V. Voronin, Alexander V. Baranov
CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
(2018)
Article
Geochemistry & Geophysics
Dmitriy A. Chareev, Mikhail V. Voronin, Evgeniy G. Osadchii
AMERICAN MINERALOGIST
(2014)
Article
Geochemistry & Geophysics
Mikhail V. Voronin, Evgeniy G. Osadchii
Article
Materials Science, Multidisciplinary
M. V. Voronin, E. G. Osadchii
INORGANIC MATERIALS
(2013)
Article
Materials Science, Characterization & Testing
F. Laufek, A. Vymazalova, D. A. Chareev, A. V. Kristavchuk, J. Drahokoupil, M. V. Voronin
POWDER DIFFRACTION
(2013)
Article
Electrochemistry
M. V. Voronin, E. G. Osadchii
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
(2011)
Article
Electrochemistry
M. V. Voronin, E. G. Osadchii
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
(2013)
Article
Geochemistry & Geophysics
V. B. Polyakov, E. G. Osadchii, M. V. Voronin, V. O. Osadchii, L. V. Sipavina, D. A. Chareev, A. V. Tyurin, V. M. Gurevich, K. S. Gavrichev
GEOCHEMISTRY INTERNATIONAL
(2019)
Article
Crystallography
R. K. Rastsvetaeva, N. V. Chukanov, L. V. Sipavina, M. V. Voronin
CRYSTALLOGRAPHY REPORTS
(2020)
Article
Materials Science, Multidisciplinary
Alexander V. Kristavchuk, Anna V. Zabolotskaya, Mikhail V. Voronin, Dmitriy A. Chareev, Evgeniy G. Osadchii
Summary: The thermodynamic properties of the kotulskite (PdTe)/merenskyite (PdTe2) equilibrium in the Ag-Pd-Te system were determined for the first time by the electromotive force (EMF) method. The results showed that the thermodynamic properties of this equilibrium reaction can be accurately determined.
PHYSICS AND CHEMISTRY OF MINERALS
(2021)
Article
Mineralogy
Tatiana A. Gvozdenko, Ivan A. Baksheev, Dmitry A. Khanin, Mikhail V. Voronin, Maria V. Chervyakovskaya, Vadim V. Smolensky
Summary: This study investigated black tourmalines from granitic pegmatites in the Murzinka pluton, Russia. Various analytical techniques were employed to determine the tourmaline's composition, including electron microprobe analysis, LA-ICP-MS, Raman spectroscopy, and Mossbauer spectroscopy. The results showed the different types and compositional evolution of tourmaline, as well as the presence of different tourmaline groups based on trace and major element composition. The Fe3+/Fe2+ ratios in tourmalines from different host rock types indicated different oxidizing environments. The Raman data supported the composition of tourmalines.
MINERALOGICAL MAGAZINE
(2022)
