A coordination strategy to realize a sextuply-bonded complex

Mo–Mo Quintuple Bond is Highly Reactive in H–H, C–H, and O–H σ-Bond Cleavages Because of the Polarized Electronic Structure in Transition State

(2017) Yue Chen et al.   INORGANIC CHEMISTRY

Development of the aza-crown ether metal complexes as artificial hydrolase

(2016) Lan Yu et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Relativistic Effects Break Periodicity in Group 6 Diatomic Molecules

(2016) Yi-Lei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Actinide (An = Th–Pu) dimetallocenes: promising candidates for metal–metal multiple bonds

(2015) Cong-Zhi Wang et al.   DALTON TRANSACTIONS

Metal–metal bonding in the actinide elements: Conceptual synthesis of a pure two-electron U–U f δ single bond in a constrained geometry of U 2 (OH) 10

(2015) Deborah A. Penchoff et al.   INORGANICA CHIMICA ACTA

Discovering complexes containing a metal–metal quintuple bond: from theory to practice

(2014) N. V. Satyachand Harisomayajula et al.   CHEMICAL COMMUNICATIONS

The Nature of the Fourth Bond in the Ground State of C2: The Quadruple Bond Conundrum

(2014) David Danovich et al.   CHEMISTRY-A EUROPEAN JOURNAL

The important role of the Mo–Mo quintuple bond in catalytic synthesis of benzene from alkynes. A theoretical study

(2014) Yue Chen et al.   DALTON TRANSACTIONS

Interconversion of Quadruply and Quintuply Bonded Molybdenum Complexes by Reductive Elimination and Oxidative Addition of Dihydrogen

(2013) Mario Carrasco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Haloacylation of the Quintuple-Bonded Group VI Metal Amidinate Dimers and Disproportionation of Acyl Groups to Form Carbynes

(2013) Han-Gung Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One Molecule, Two Atoms, Three Views, Four Bonds?

(2013) Sason Shaik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent reactivity of nitric oxide with metal–metal quintuple bonds

(2013) Pei-Fang Wu et al.   CHEMICAL COMMUNICATIONS

Does the metal–metal sextuple bond exist in the bimetallic sandwich compounds Cr2(C6H6)2, Mo2(C6H6)2, and W2(C6H6)2?†

(2013) Zhi Sun et al.   MOLECULAR PHYSICS

An Electron-Rich Molybdenum-Molybdenum Quintuple Bond Spanned by One Lithium Atom

(2012) Shin-Cheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of Metal-Metal Quintuple Bonds with Alkynes: [2+2+2] and [2+2] Cycloadditions

(2012) Hong-Zhang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

(2012) Mario Carrasco et al.   CHEMICAL COMMUNICATIONS

Assessing Metal-Metal Multiple Bonds in CrCr, MoMo, and WW Compounds and a Hypothetical UU Compound: A Quantum Chemical Study Comparing DFT and Multireference Methods

(2012) Giovanni Li Manni et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quintuple Bond Reactivity toward Group 16 and 17 Elements: Addition vs Insertion

(2012) Emmanuel Sobgwi Tamne et al.   INORGANIC CHEMISTRY

Quadruple bonding in C2 and analogous eight-valence electron species

(2012) Sason Shaik et al.   Nature Chemistry

Formation of cyclo-E42− Units (E4=P4, As4, AsP3) by a Complex with a CrCr Quintuple Bond

(2011) Christoph Schwarzmaier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of a quintuply bonded chromium dimer with alkynes

(2011) Jingmei Shen et al.   CHEMICAL COMMUNICATIONS

Cycloaddition Reactions of a Chromium-Chromium Quintuple Bond

(2011) Awal Noor et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bonding Analysis of Metal−Metal Multiple Bonds in R3M−M′R3(M, M′ = Cr, Mo, W; R = Cl, NMe2)

(2011) Nozomi Takagi et al.   INORGANIC CHEMISTRY

Electronic structure and chemical bonding in W2 molecule

(2010) Antonio Carlos Borin et al.   CHEMICAL PHYSICS LETTERS

On the Analysis of the Cr−Cr Multiple Bond in Several Classes of Dichromium Compounds

(2010) G. La Macchia et al.   INORGANIC CHEMISTRY

Metal−Metal Quintuple and Sextuple Bonding in Bent Dimetallocenes of the Third Row Transition Metals

(2010) Bing Xu et al.   Journal of Chemical Theory and Computation

Reactions of Ar′CrCrAr′ with N2O or N3(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

(2009) Chengbao Ni et al.   CHEMICAL COMMUNICATIONS

Analysing the chromium–chromium multiple bonds using multiconfigurational quantum chemistry

(2009) Marcin Brynda et al.   CHEMICAL PHYSICS LETTERS

BS DFT and BS HDFT studies of CrCr sextuple bond from the viewpoint of electron correlation effects

(2009) Yasutaka Kitagawa et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

Journey from Mo−Mo Quadruple Bonds to Quintuple Bonds

(2009) Yi-Chou Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboalumination of a chromium–chromium quintuple bond

(2009) Awal Noor et al.   Nature Chemistry

Ultrashort metal–metal distances and extreme bond orders

(2009) Frank R. Wagner et al.   Nature Chemistry

Metal-Metal Distances at the Limit: Cr-Cr 1.73 Å - the Importance of the Ligand and its Fine Tuning

(2009) Awal Noor et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Metal-Metal Distances at the Limit: A Coordination Compound with an Ultrashort Chromium-Chromium Bond

(2008) Awal Noor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quintuply-Bonded Dichromium(I) Complexes Featuring Metal-Metal Bond Lengths of 1.74 Å

(2008) Chia-Wei Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A theoretical study of the binding and electronic spectrum of the Mo2 molecule

(2007) Antonio Carlos Borin et al.   CHEMICAL PHYSICS