Journal
OXIDATION OF METALS
Volume 89, Issue 5-6, Pages 683-697Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11085-017-9811-8
Keywords
Ni-based alloys; High-temperature corrosion; Carburization; Supercritical carbon dioxide
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Funding
- Engineering Research Center Program of MSIP/NRF [2016R1A5A1013919]
- MOTIE/KETEP of Korea [20161110100120]
- Korea Institute of Materials Science (KIMS)
- BK-Plus Program of the MSIP of Korea
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Pure Ni and Ni-xCr (x = 7, 14, 22 and 27 wt%) binary alloys were exposed to supercritical-carbon dioxide environment at 600 degrees C and 20 MPa for 200 h. For pure Ni, a thick NiO layer was formed on the surface. Meanwhile, for Ni-7Cr alloy, an inner oxide layer consisted of rather irregular chromia and NiO was formed below the outer NiO layer. When Cr content was greater than 14%, a continuous chromia layer was formed, resulting in much lower weight gain and oxide thickness. However, amorphous carbon layers had developed along the oxide-matrix interface when chromia was formed. The presence of the carbon layer was explained in view of the high C activity corresponding to the low equilibrium oxygen potential of chromia.
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