Journal
ORGANOMETALLICS
Volume 36, Issue 7, Pages 1217-1219Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00022
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Funding
- National Natural Science Foundation of China [81172952]
- Foundation for University Key Teacher by the Education Department of Henan Province [137]
- program for Science & Technology Innovation Talents in Universities of Henan Province [17HASTIT043]
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The preparation of cis-2,3-dihydrobenzofuranols with two stereocenters through aqueous asymmetric transfer hydrogenation (ATH) of benzofuranones with the metal catalyst Ru(II) via dynamic kinetic resolution (DKR) has been developed. A variety of alpha-alkyl benzofuranones were transformed to obtain optically pure 2,3-dihydrobenzofuran-3-ols with excellent enantioselectivities and acceptable yields under mild conditions.
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