Journal
ORGANIC LETTERS
Volume 19, Issue 24, Pages 6470-6473Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02967
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Funding
- National Natural Science Foundation of China [21402124, 51673117]
- Training Foundation for Outstanding Young Teachers in Higher Education Institutions of Guangdong [YQ2015145]
- Shenzhen Science and Technology Foundation [JCYJ20150324141711702, JCYJ20170302143658923, JCYJ20150529164656097, JCYJ20150625102750478]
- Natural Science Foundation of SZU [827000038]
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The first solid-supported directed aromatic C-H activation/acetoxylation has been successfully developed by using palladium nanoparticles supported on graphene oxide (PdNPs/GO) as a catalyst. The practicability of this method is demonstrated by, simple preparation of catalyst, high catalytic efficiency, wide functional group tolerance, and easy scale up of the reaction. A hot filtration test and Hg(0) poisoning test indicate the heterogeneous nature of the catalytic active species.
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