Journal
ORGANIC LETTERS
Volume 19, Issue 18, Pages 4722-4725Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02009
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Funding
- National Science Foundation [CHE 1465189]
- Alexander v. Humboldt Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1465189] Funding Source: National Science Foundation
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Rh(II)-catalyzed enantioselective cyclopropanations of furans, providing access to synthetically useful building blocks, are reported. After screening of 10 Rh(II) catalysts, Rh-2(S-TCPTTL)(4) was identified as a highly efficient and selective catalyst (up to 98% ee, TON 88000, and TOF 24/s) for the cydopropanation of furans. These cyclopropanes were successfully applied to the enantioselective synthesis of novel paraconic acid derivatives.
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