Journal
ORGANIC LETTERS
Volume 19, Issue 6, Pages 1430-1433Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00367
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- JST
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A silver-catalyzed chlorination of benzylic, tertiary, and secondary C(sp(3)) H bonds was developed. The reaction proceeded with as low as 0.2 mol % catalyst loading at room temperature under air atmosphere with synthetically useful functional group compatibility. The regioselectivity and reactivity tendencies suggest that the chlorination proceeded through a radical pathway, but an intermediate alkylsilver species cannot be ruled out.
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