Journal
ORGANIC LETTERS
Volume 19, Issue 14, Pages 3931-3934Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01853
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Funding
- NSFC/China [21672060, 21421004, 21420102004]
- Fundamental Research Funds for the Central Universities [WJ1616011, WJ1213007, 222201717003]
- Programme of Introducing Talents of Discipline to Universities [B16017]
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A novel braided hetero[2](3)rotaxane is demonstrated by integrating the braided structure and mechanically interlocked rotaxane, in which a heterotritopic linear tris(dialkylammonium) guest penetrates a heterotritopic tris(crown ether) host, resulting in the formation of braided pseudohetero[2](3)rotaxane with different crossing and threading points. Then a braided hetero[2](3)rotaxane is constructed through the CuAAC click reaction.
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