Metal-free radical aromatic carbonylations mediated by weak bases

A study of diketopiperazines as electron-donor initiators in transition metal-free haloarene–arene coupling

(2017) Florimond Cumine et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Spirocyclohexadienones through Radical Cascade Reactions Featuring 3-Fold Carbon–Carbon Bond Formation

(2017) Nina Hegmann et al.   ORGANIC LETTERS

Transition-Metal-Free β-C–H Bond Carbonylation of Enamides or Amides with a Trifluoromethyl Group as CO Surrogate for the Synthesis of 1,3-Oxazin-6-ones

(2017) Ping Song et al.   ORGANIC LETTERS

Double Deprotonation of Pyridinols Generates Potent Organic Electron-Donor Initiators for Haloarene-Arene Coupling

(2016) Joshua P. Barham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts

(2016) Stephanie Kindt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: Asymmetric Catalytic Aza-Diels-Alder/Ring-Closing Cascade Reaction Forming Bicyclic Azaheterocycles by Trienamine Catalysis (Chem. Eur. J. 1/2017)

(2016) Yang Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition metal-free, iodide-mediated domino carbonylation–benzylation of benzyl chlorides with arylboronic acids under ambient pressure of carbon monoxide

(2016) Fengli Jin et al.   GREEN CHEMISTRY

Transition Metal Catalyst-Free and Radical Initiator-Free Carbonylation of Aryl Iodides

(2016) Shinsuke Fukuoka   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Curiosity-Driven Research on Acyl Radicals

(2016) Ilhyong Ryu   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

KOtBu: A Privileged Reagent for Electron Transfer Reactions?

(2016) Joshua P. Barham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Alkoxycarbonylation of Unactivated Secondary Alkyl Bromides at Low Pressure

(2016) Brendon T. Sargent et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free radical thiolations mediated by very weak bases

(2016) Denis Koziakov et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Radical arylation of tyrosine residues in peptides

(2016) Stefanie K. Fehler et al.   TETRAHEDRON

C–C bond-forming reactions of ground-state aryl halides under reductive activation

(2016) Katie J. Emery et al.   TETRAHEDRON

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Aminocarbonylation of Aryl Iodides

(2015) Takuji Kawamoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible Light Driven Hydro-/Deuterodefunctionalization of Anilines

(2015) Michal Majek et al.   CHEMISTRY-A EUROPEAN JOURNAL

Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts

(2015) Stephanie Kindt et al.   ORGANIC LETTERS

Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts

(2014) Shuhei Sumino et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Free, Room-Temperature, Radical Alkoxycarbonylation of Aryldiazonium Salts through Visible-Light Photoredox Catalysis

(2014) Wei Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Carbonylations by Photoredox Catalysis

(2014) Michal Majek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ascorbic Acid as an Initiator for the Direct CH Arylation of (Hetero)arenes with Anilines Nitrosated In Situ

(2014) Fernando Pinacho Crisóstomo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

Organocatalytic visible light mediated synthesis of aryl sulfides

(2013) Michal Majek et al.   CHEMICAL COMMUNICATIONS

Recent applications of arene diazonium salts in organic synthesis

(2013) Fanyang Mo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organic super-electron-donors: initiators in transition metal-free haloarene–arene coupling

(2013) Shengze Zhou et al.   Chemical Science

Transition-Metal-Free Alkoxycarbonylation of Aryl Halides

(2012) Hua Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl Diazonium versus Iodonium Salts: Preparation, Applications and Mechanisms for the Suzuki-Miyaura Cross-Coupling Reaction

(2011) Hélène Bonin et al.   ADVANCED SYNTHESIS & CATALYSIS

Evolution and Synthetic Applications of the Heck-Matsuda Reaction: The Return of Arenediazonium Salts to Prominence

(2011) Jason G. Taylor et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

The first intramolecular Heck–Matsuda reaction and its application in the syntheses of benzofurans and indoles

(2010) Fernanda A. Siqueira et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION