Niobium(v)-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C–F bond activation

Single C−F Bond Cleavage of Trifluoromethylarenes with an ortho -Silyl Group

(2016) Suguru Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic activation of a single C–F bond in trifluoromethyl arenes

(2016) Hester Dang et al.   Chemical Science

Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes

(2015) Takayuki Yamada et al.   ADVANCED SYNTHESIS & CATALYSIS

Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination

(2015) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate

(2015) Ryohei Doi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Review of recent advances in CF bond activation of aliphatic fluorides

(2015) Qian Shen et al.   JOURNAL OF FLUORINE CHEMISTRY

Carbon–fluorine bond activation for the synthesis of functionalized molecules

(2015) Teresa A. Unzner et al.   TETRAHEDRON LETTERS

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species

(2013) Mike Ahrens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrodefluorinations of trifluorotoluenes by LiAlH4 and TiCl4

(2013) Takahiko Akiyama et al.   JOURNAL OF FLUORINE CHEMISTRY

C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling Nucleophilic Substitution Reactions of Activated Alkyl Fluorides through Hydrogen Bonding

(2013) Pier Alexandre Champagne et al.   ORGANIC LETTERS

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

Protolytic defluorination of trifluoromethyl-substituted arenes

(2011) Anila Kethe et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

AlCl3-mediated Defluorinative Diarylhydroxylation Transformation of CF3: Chemoselective Arylation of CF3and Chlorocarbonyl Groups Attached to Aromatic Rings

(2010) Akiko Okamoto et al.   CHEMISTRY LETTERS

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Synthesis of N-Fused Indoles: A CF Activation and CH Insertion Approach

(2009) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents

(2009) Jun Terao et al.   CHEMICAL COMMUNICATIONS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Brønsted Acid Mediated (sp3)Carbon-Fluorine Bond Activation: Inter- and Intramolecular Arylation of Trifluoromethylated Arenes

(2009) Fei WANG et al.   CHINESE JOURNAL OF CHEMISTRY

Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis

(2009) Weixing Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS