Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 35, Pages 7272-7276Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob01766a
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- DST-MPI partner programme
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The first organocatalytic asymmetric reaction of acyclic enecarba-mates with o-quinone methides is disclosed. BINOL-based phosphoric acid catalysts were found to be suitable for the annulation reaction. With 10 mol% of the TRIP catalyst, high yields as well as excellent diastereo- and enantioselectivities are achieved for a variety of 2,3,4-trisubstituted chroman products.
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