Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 18, Pages 3863-3868Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00599g
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Funding
- National Natural Science Foundation of China [21662029, 21262027]
- Young Scientists Foundation of Shihezi University [RCZX201546, 2015ZRKXJQ05]
- Excellent Young Teachers Plan of Bingtuan
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A novel organocatalytic olefinic carbon-sulfur bond forming reaction was developed. Under the catalysis of 10 mol% stable N-heterocyclic carbene, thiols undergo direct nucleophilic substitution reaction with gem-difluoroalkenes to produce alpha-fluorovinyl thioethers in high yields with excellent Z-selectivity. In this process, bases are not necessary.
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