Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 27, Pages 5685-5688Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob01123g
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- University of Milan
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Cyclopentadienone-based iron complexes were used for the first time to successfully catalyze the diastereoselective hydrogenation of enantiopure imines. Chiral amines, including valuable biologically active products, were obtained often as enantiomerically pure compounds. Computational studies helped to elucidate the chemical and stereochemical aspects of the iron-catalyzed reaction.
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