Journal
NUCLEAR SCIENCE AND TECHNIQUES
Volume 28, Issue 7, Pages -Publisher
SPRINGER SINGAPORE PTE LTD
DOI: 10.1007/s41365-017-0251-6
Keywords
Uranium; Adsorption; Kinetics; Isotherms; Sintering
Categories
Funding
- National Natural Science Foundation of China [U1532259]
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Amidoxime-functionalized ultra-high molecular weight polyethylene fibers (UHMWPEF-AO) were used to absorb uranium U(VI) from aqueous solutions. In this paper, we study effects of pH, initial U(VI) concentration, contact time, and temperature on U(VI) adsorption by UHMWPEF-AO. The adsorption process agrees well with pseudo-second-order and Langmuir model. UHMWPEF-AO exhibits excellent adsorptive performance for U(VI) with a maximum adsorption capacity of 176.12 mg/g at pH 4 and 298 K. The structures of UHMWPEF-AO and U(VI)-loaded UHMWPEF-AO are characterized by FT-IR and nano-CT. U(VI)-loaded UHMWPEF-AO is sintered after adsorption process to recycle absorbed U(VI). Powders collected after sintering process are examined by scanning electron microscopy and X-ray diffraction. These results indicate that UHMWPEF-AO is a promising candidate to remove U(VI) from uranium aqueous solutions.
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