Journal
NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 1, Pages 51-55Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj02785g
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Funding
- National Natural Science Foundation of China [21402208, 21533011, 21125314]
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Polyureas derived from CO2 and diamines were effective for C-H arylation of benzene in the presence of t-BuOK, producing biaryl products with various substituents in high yields up to 97%. Dual-activation of K+ and t-BuO-, and pi,pi-stacking interaction between the substrate and the polymer backbone may account for the superior activity.
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