Article
Polymer Science
An Nang Vu, Hoa Ngoc Thi Le, Thang Bach Phan, Hieu Van Le
Summary: This article introduces a novel effluent treatment solution using noble metal-based nanocatalysts and NaBH4 as a reducing agent. The researchers propose a simple method to synthesize magnetic cellulose nanocrystals modified with magnetite and silver nanoparticles as a catalyst without using any reducing agents or stabilizers. The nanocomposite shows excellent catalytic degradation performance for organic pollutants and can be reused multiple times.
Article
Chemistry, Multidisciplinary
Phyu Phyu Cho, Phyu Phyu Mon, Devthade Vidyasagar, Giridhar Madras, Ch. Subrahmanyam
Summary: A heterojunction of oxide perovskite (Bi2MoO6) dispersed on polymeric carbon nitride (PCN) sheets was prepared using solvothermal and thermal pyrolysis approaches. The introduction of Bi2MoO6 particles onto the PCN sheets enhanced light absorption characteristics of the heterojunction. The resulting heterojunction had a larger surface area and demonstrated accelerated reduction kinetics compared to the individual catalysts.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Environmental Sciences
Parth Shah, Kartik Joshi, Manan Shah, Ashish Unnarkat, Femina J. Patel
Summary: Coloured wastewater is a significant issue for human health and ecology, and photocatalysis shows promise for its complete degradation. This study synthesized NiFe2O4 and modified it by creating composites with TiO2. The results demonstrate that NiFe2O4-based nanocomposites can serve as effective and magnetic retrievable photocatalysts.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Engineering, Electrical & Electronic
Krishnasamy Lakshmi, Ragunathan Jayashri, Krishna Kadirvelu
Summary: Increased industrial activity has resulted in the release of large quantities of phenolic compounds and their derivatives into the environment, with 4-nitrophenol being particularly harmful to human organs. A newly developed fluorescent nanocomposite CQDs@CeO2 shows exceptional properties and has high efficiency in reducing 4-nitrophenol.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Biochemistry & Molecular Biology
Suresh Velpula, Sashidhar Rao Beedu, Karuna Rupula
Summary: In this study, bimetallic Ag-Au, Ag-Pd, and Au-Pd nanoparticles were synthesized using a natural biopolymer gum kondagogu as a reducing and capping agent. Characterization of the nanoparticles showed different catalytic efficiencies in the reduction of 4-nitrophenol, with Ag-Pd exhibiting the highest efficiency among the three.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Chemistry, Multidisciplinary
Mirshad Amraei, Saeed Farhadi, Abdolnasar Mohammadi-Gholami
Summary: In this study, a novel Ag@NiFe2O4/MIL101(Fe) ternary magnetic nanocomposite was synthesized and its catalytic reduction activity for nitrophenols and nitroanilines was investigated. The results showed that the nanocomposite exhibited excellent performance in the conversion of these contaminants.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Environmental Sciences
Ashwini S. Varpe, Mrinalini D. Deshpande, Dipak R. Tope, Ashok V. Borhade
Summary: CdFe2O4/Al2O3 magnetic nanocomposite photocatalyst is synthesized by sol-gel auto-combustion method, and its role as a photocatalyst is studied. The influence of Al2O3 concentration on the photocatalytic property is investigated. The 10% composite sample shows superior properties compared to other concentrations and bare CdFe2O4 nanoparticles. The degradation rate of xylenol orange dye reaches 92.29% after 30 minutes of photocatalytic reaction.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Multidisciplinary Sciences
A. G. Ramu, Dongjin Choi
Summary: Azo dyes and nitrophenols are widely used in industries but are highly toxic to aquatic organisms. In this study, a low-cost PdO-doped NiO hetero-mixture was synthesized and found to have excellent catalytic activity, high reduction rates, and stable performance in reducing toxic azo compounds. The PdO-NiO catalyst could be a promising solution for the degradation of azo compounds in the environment.
SCIENTIFIC REPORTS
(2021)
Article
Engineering, Electrical & Electronic
Z. Ghubish, R. Kamal, Hala R. Mahmoud, M. Saif, H. Hafez, M. El-Kemary
Summary: The utilization of Ag-doped SrSnO3 for photocatalytic reduction of pollutants has been studied. The results show that 2.0wt% Ag-doped SrSnO3 exhibits efficient photocatalytic reduction of 4-NP and mineralization of MB.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Physical
Hanan A. Albalwi
Summary: This study aimed to investigate the degradation of Direct Red 83 dye using Ca-ALG/MgO/Ag nanocomposite beads as a catalyst. The formation of nanocomposite beads was confirmed by various analyses. The effects of different operating parameters were carefully studied to find the optimum degradation conditions. The results showed that the Ca-ALG/MgO/Ag nanocomposite beads were efficient for the degradation of Direct Red 83 dye, achieving a degradation efficiency of approximately 95%.
Article
Engineering, Environmental
Heba Ali, A. M. Ismail
Summary: This study presents the in-situ synthesis of recyclable bio-nanocomposite beads based on chitosan (Cs) and silver (Ag) nanoparticles for catalytic processes. The prepared beads showed high catalytic activity in the hydrogenation of nitrophenol. The immobilization of Ag into Cs beads was confirmed, and the average diameter of the grown Ag atoms was approximately 6.7 nm. Regeneration studies also demonstrated the catalytic stability of the beads. The mechanism of the fabrication of Ag@Cs biocomposite hydrogel beads in a single pot was thoroughly discussed.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Article
Polymer Science
Mehreen Iqbal, Zain-ul-Abdin, Taiba Naseem, Muhammad Waseem, Salah Ud Din, Muhammad Hafeez, Sirajul Haq, Sadia Qureshi, Asia Bibi, Shams Ur Rehman, Rafaqat Hussain
Summary: Water pollution is a significant ecological issue that poses serious problems to human health. Developing cost-effective advanced technologies for water purification, such as nanocomposites like rGO/Ag2O, is crucial. These nanocomposites demonstrate effective catalytic and photocatalytic activity in wastewater treatment, showing promise for addressing pollution issues.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Vandana P. Viswanathan, K. S. Divya, Deepak P. Dubal, Nayarassery N. Adarsh, Suresh Mathew
Summary: The paper discusses the efficient integration of a plasmonic photocatalyst with an iron-based metal-organic framework to enhance visible light photoreactivity. The hybrid system shows excellent photocatalytic activity for the degradation of organic compounds under sunlight, attributed to the synergistic effects of surface plasmon resonance and electron transfer.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Yu Zhang, Chao Li, Xianfu Liu, Jing Xu, Xingkun Yang, Zhang Zhang
Summary: A green and cost-effective strategy was developed to prepare platinum/graphene aerogel nanocomposites, which showed outstanding catalytic performance in the reduction of nitroaromatic compounds. Pt/GA-2 catalyst synthesized with a mass ratio of 2:1 exhibited the lowest activation energy value and promising prospects for industrial applications in wastewater treatment.
GREEN ENERGY & ENVIRONMENT
(2021)
Article
Materials Science, Multidisciplinary
Jawaria Fatima, M. Bilal Tahir, M. Suleman Tahir, M. Sagir
Summary: This study presents a novel MXene material and fabricates nano-composites based on Ti2C MXene and ZnCo2O4. The experimental results demonstrate that the addition of ZnCo2O4 can enhance the photo-catalytic performance of Ti2C composites.
Article
Chemistry, Physical
Zhengcui Wu, Yejing Xue, Zexian Zou, Xia Wang, Feng Gao
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2017)
Article
Nanoscience & Nanotechnology
Zhengcui Wu, Zexian Zou, Jiansong Huang, Feng Gao
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Electrochemistry
Zhengcui Wu, Jingjing Li, Zexian Zou, Xia Wang
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2018)
Article
Chemistry, Physical
Zhengcui Wu, Xia Wang, Jiansong Huang, Feng Gao
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Electrochemistry
Xiangyu Wang, Wuzhengzhi Zhang, Junliang Zhang, Zhengcui Wu
Article
Chemistry, Physical
Manyu Yang, Junliang Zhang, Wuzhengzhi Zhang, Zhengcui Wu, Feng Gao
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Chemistry, Multidisciplinary
Junliang Zhang, Weipei Sun, Lianchun Ding, Zhengcui Wu, Feng Gao
Summary: Au nanocrystals@defective amorphous MnO2 nanosheets core/shell nanostructure was developed for efficient CO2 electroreduction to CO. The optimized structure with 60 nm nanosheets shell size achieved the highest faradic efficiency for CO production and exhibited excellent stability.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Electrochemistry
Xiangyu Wang, Wuzhengzhi Zhang, Junliang Zhang, Jing Zhang, Zhengcui Wu
Summary: The incorporation of Cu2+ ions in Co(OH)(2) catalyst improves its electronic structure, activates active sites, and enhances performance in urea-assisted electrolytic hydrogen generation. This doping strategy can be extended to Ni-based compounds to boost the activities of urea oxidation and hydrogen evolution reactions.
Article
Chemistry, Inorganic & Nuclear
Wuzhengzhi Zhang, Lianchun Ding, Weipei Sun, Zhengcui Wu, Zheng Chen, Feng Gao
Summary: In this study, Br-doped CuO multilamellar mesoporous nanosheets were successfully synthesized on Cu foam to serve as highly active and selective electrocatalysts for the CO2 electroreduction reaction (CO2ER) into ethanol. The introduction of Br- ions induced oxygen vacancies, while adsorbed CTA(+) cations modulated the O affinity of Cu sites, optimizing intermediate species and their adsorption behaviors. The optimized Br1.95%-CuO catalyst showed excellent catalytic stability and achieved a high faradaic efficiency of 53.3% for C2H5OH production.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Wuzhengzhi Zhang, Lianchun Ding, Weipei Sun, Tian Sheng, Zhengcui Wu, Feng Gao
Summary: In this study, a Pt nanoparticles-loaded crystalline MoO2/amorphous Ni(OH)2 hybrid nanosheets-composed nanofilm was successfully designed via a one-step solution-phase strategy for efficient alkaline hydrogen evolution reaction (HER). The hybrid nanosheets structure utilized in the catalyst accelerated water dissociation and optimized the utilization of dissociated H atoms, resulting in enhanced HER performance. The density functional theory results indicated thermodynamically favored water dissociation at Pt/Ni(OH)2 and reduced energy barriers for hydrogen adsorption, showcasing the potential for practical applications in hydrogen generation.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Inorganic & Nuclear
Wuzhengzhi Zhang, Nannan Zhu, Lianchun Ding, Yan Hu, Zhengcui Wu
Summary: Researchers have developed Ag NPs/CuO MNSs heterostructure with optimized catalytic activity and selectivity for CO2ER to CO. The optimal catalyst Ag-1.01%/CuO exhibits high catalytic efficiency and stability at -0.7 V.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Lianchun Ding, Nannan Zhu, Yan Hu, Zheng Chen, Pin Song, Tian Sheng, Zhengcui Wu, Yujie Xiong
Summary: This study demonstrates a versatile method to tune the interaction between Cu sites and reaction intermediates in CO2 electroreduction towards high selective ethanol production by doping K in Cu2Se nanosheets array. The optimized K-11.2%-Cu2Se nanosheets array exhibits high selectivity for ethanol production with a Faradaic efficiency of 70.3% at -0.8V, and remains stable for 130 hours.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Yan Hu, Jiahui Zhu, Nannan Chen, Xinyue Zheng, Xingyue Zhang, Zheng Chen, Zhengcui Wu
Summary: This study designs a Sr-doped CuO catalyst with a hydrophobic surface for selective electroreduction of CO2 to ethane. Sr doping enhances CO2 adsorption and coupling reactions, while the hydrophobic surface promotes the conversion of intermediates to ethane. The optimized catalyst exhibits high selectivity and efficiency for ethane production.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Zexian Zou, Xiangyu Wang, Jiansong Huang, Zhengcui Wu, Feng Gao
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)