4.6 Article

A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

Journal

NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 21, Pages 12830-12834

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj03443a

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Funding

  1. Xunta de Galicia (REGALIs Network) [R2014/015]

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A new procedure to prepare epsilon-caprolactam by the Beckmann rearrangement of cyclohexanone oxime is described. Treatment of the oxime with the novel salt cyanoguanidinium tosylate affords epsilon-caprolactam without the need of any other promoter.

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