Article
Chemistry, Physical
Ya Bai, Jinjia Liu, Tao Wang, Yu-Fei Song, Yong Yang, Yong-Wang Li, Xiaodong Wen
Summary: In this study, a unified calculation method was used to explore the adsorption, dissociation, and reduction behaviors of hydrogen on Fe5C2 surfaces. The results showed that the dissociation of hydrogen molecule is thermodynamically and kinetically favorable, and it strongly affects the adsorption energy. Furthermore, the equilibrium crystalline morphology evolution of Fe5C2 was constructed using Wulff theorem, and the reduction process of carbon vacancies was investigated.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Seunghee Cha, Heewon Kim, Hyunkyung Choi, Chul Sung Kim, Kyoung-Su Ha
Summary: Chi-Fe5C2, a highly active phase in Fischer-Tropsch synthesis, was successfully synthesized using a wet-chemical route without the need for pre-activation. The encapsulation of chi-Fe5C2 nanoparticles with mesoporous silica was found to effectively protect them from deactivation and re-oxidation, while maintaining their phase intact. The CO2 selectivity of stabilized chi-Fe5C2 was very low, indicating its potential as a catalyst for Fischer-Tropsch synthesis.
Article
Chemistry, Physical
Huabo Zhao, Hong Jiang, Meng Cheng, Quan Lin, Yijun Lv, Yao Xu, Junzhong Xie, Jin-xun Liu, Zhuowu Men, Ding Ma
Summary: Boron adsorption on the chi-Fe5C2 catalyst can improve its stability and activity, suppress coking, and expose more active planes to facilitate CO activation. Co-adsorbed boron atoms have little impact on the barrier of CO direct dissociation in most cases, but can activate CO on boron with carbon termination in specific situations.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Chemistry, Physical
Michael Claeys, Eric van Steen, Thys Botha, Renier Crous, Alta Ferreira, Avinash Harilal, Denzil James Moodley, Prabashini Moodley, Esna du Plessis, Jacobus L. Visagie
Summary: Flagg carbide is considered the primary active phase in high-temperature iron-based Fischer-Tropsch synthesis. Its oxidation to magnetite may lead to loss of FT activity, but this transformation can be reversed by adjusting the water vapor partial pressure. Magnetite is believed to be active in the water-gas shift reaction, but may not solely be responsible for this activity during the FTS process.
Article
Chemistry, Physical
Yu Zhang, Ke Xie, Fangyao Zhou, Feiteng Wang, Qian Xu, Jun Hu, Honghe Ding, Peng Li, Yi Tan, Deming Li, Junfa Zhu, Huang Zhou, Changming Zhao, Sen Lin, Yuen Wu
Summary: Under the crisis of the COVID-19 pandemic, a shortage of medical-grade oxygen is being faced globally. A new oxygen generation device based on electrochemical technology has been developed, which can produce high purity oxygen quickly and stably for a long period of time. The device is portable, has fast response time, and operates quietly, showing potential to replace traditional oxygen production equipment.
ADVANCED ENERGY MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Jingyi Wang, Ting Lei
Summary: This article discusses the separation methods for enriching large-diameter s-SWCNTs and their advantages in electronic applications, including CPW, GC, ATPE, and DGU technologies. By separating based on the electronic type and chirality of SWCNTs, important references can be provided for the future development of SWCNT-based electronic devices.
Article
Metallurgy & Metallurgical Engineering
L. A. Pasechnik, V. M. Skachkov, A. Yu Chufarov, A. Yu Suntsov, S. P. Yatsenko
Summary: Storage of red mud, a byproduct of bauxite processing, can lead to environmental issues due to its high alkalinity and particle dispersity. Scandium, the most valuable component of red mud, is poorly commercialized because of extraction costs, however, new efficient extraction technologies promise to reduce costs significantly. By sulfatising scandium concentrate extracted from red mud, silica can be separated from water-soluble sulfates, while crystallization of scandium and ammonium sulfates offers a selective separation method with high solubility in water.
Article
Engineering, Electrical & Electronic
Archita Hati, Craig W. Nelson
Summary: We propose a simple method for adjusting the in-phase (I) and quadrature-phase (Q) Armstrong-type modulator as a calibrator for precision noise metrology. The method can correct for the phase and amplitude imbalance in IQ modulators without the need for a calibrated IQ demodulator. Calibration results show that the modulator can provide high-purity AM/PM signals with spurious modulations as low as 1 ppm when used as a calibrator for a PM and AM noise measurement system.
IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT
(2022)
Article
Energy & Fuels
Sanchao Liu, Huihui He, Dongyun Zhang, Chengkang Chang
Summary: Cr-doped LiCoMn1-xCrxO₄ materials were synthesized at 750 degrees C, which increased the phase purity and stability of the cathode material, leading to improved electrochemical performance such as higher specific capacity, enhanced capacity retention, and promoted rate performance. The presence of Cr in the lattice structure also contributed to the increase in lithium ion diffusion coefficient.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Fei Zhu, Wei-Li Song, Jianbang Ge, Zhe Wang, Zheng Huang, Shijie Li, Mingyong Wang, Haibin Zuo, Shuqiang Jiao, Hongmin Zhu
Summary: Petroleum coke (PC) is widely used as raw materials for electrodes, but it also produces large amounts of CO2 gases. To reduce CO2 emissions, a catalyst-free process is proposed to convert high-sulfur PC into graphitic nanomaterials. The process has lower energy consumption and the resulting graphite materials have competitive specific capacity for energy storage.
Article
Engineering, Environmental
Liming Yang, Zhe Gao, Tian Liu, Meiting Huang, Guangzhen Liu, Yufa Feng, Penghui Shao, Xubiao Luo
Summary: Recovering lithium from spent ternary lithium batteries (T-LIBs) is a promising approach for sustainable T-LIB development. Chemical leaching methods, widely used in current lithium recovery, pose serious environmental threats and result in low Li recovery purity. In this study, we present a direct electro-oxidation method for lithium leaching, achieving high Li recovery purity of nearly 100% without secondary pollution.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Zhongmin Hou, Xiaomin Wang, Jidong Li, Zhen Li, Yiyong Wang, Hongxuan Xing
Summary: In this study, the electrochemical behavior of indium was investigated using different electrochemical methods. It was found that the electrodeposition process of indium is irreversible. The average charge transfer coefficient of In3+ was determined using cyclic voltammetry. The nucleation mechanism of indium was analyzed using chronoamperometry, and the reduction process of In3+ was studied using alternating current impedance. SEM and XRD techniques confirmed the purity of the cathodic products deposited on the titanium electrode.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Donghao Xie, Miao Zhang, Qirong Liu, Yunjie Lin, Ao Yu, Yongbing Tang
Summary: A scalable and highly efficient approach for the preparation of high-purity 2D metal nanosheets has been developed using organic-inorganic conformal extending procedures. The approach achieves uniform and controllable thickness of metal nanosheets while avoiding the introduction of impurities. As a proof-of-the-concept application, a compact hybrid anode constructed from Sn nanosheets and graphene oxide exhibits high reversible capacity and excellent cycling stability. This methodology is expected to facilitate the fundamental research and applications of 2D metal nanosheets in various important fields.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Guangyu Wang, Hao Wu, Yiming Liu, Yiwei Pang, Junsheng Hao, Fangqin Cheng, Aniu Qian, Hu Shi
Summary: We have identified the role of -CF3 terminations in the surface structure of Ti3C2Tx during delamination using ethanol and water as solvents. Ethanol-treated -CF3-terminated Ti3C2Tx exhibits enhanced capacitive properties in ionic liquid, including prevention of nanoflake aggregation, hydrophobicity, and small size, compared to water-treated Ti3C2Tx in both aqueous and ionic liquid electrolytes.
CHEMICAL COMMUNICATIONS
(2023)
Article
Electrochemistry
Jagadeesh Sure, D. Sri Maha Vishnu, Sunghun Choi, Hyun-Kyung Kim, Carsten Schwandt
Summary: Nano-sized powders of Ta1-xHfxC ceramics were synthesized by electro-deoxidation method at a significantly lower temperature than the conventional preparation methods. The synthesized ceramics exhibited excellent crystal structure and particle size distribution, and had better control over composition.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Review
Chemistry, Physical
Haneesh Saini, Eva Otyepkova, Andreas Schneemann, Radek Zboril, Michal Otyepka, Roland A. Fischer, Kolleboyina Jayaramulu
Summary: Oil contaminated water is a global issue, and metal-organic frameworks (MOFs) with special wettability show promising potential for oil/water separation. Their highly tunable structure and properties make them suitable for various applications in oily water treatment.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Vishwas G. Chandrashekhar, Thirusangumurugan Senthamarai, Ravishankar G. Kadam, Ondrej Malina, Josef Kaslik, Radek Zboril, Manoj B. Gawande, Rajenahally Jagadeesh, Matthias Beller
Summary: Development of an iron-based catalyst for hydrogenation of nitriles, capable of promoting the conversion of various nitriles into primary amines under scalable and industrially viable conditions.
Article
Nanoscience & Nanotechnology
Aby Cheruvathoor Poulose, Giorgio Zoppellaro, Ioannis Konidakis, Efthymis Serpetzoglou, Emmanuel Stratakis, Ondrej Tomanec, Matthias Beller, Aristides Bakandritsos, Radek Zboril
Summary: This study reports a low-cost plasmonic photocatalyst based on earth-abundant metals that achieves selective hydrogenation of nitroaromatics through the combined action of photothermal effects and hot holes. The catalyst operates under solar light and delivers high conversion rates by matching energy levels. The findings have significant implications for improving production rates in industries such as polymers, pharmaceuticals, agrochemicals, and dyes.
NATURE NANOTECHNOLOGY
(2022)
Article
Chemistry, Physical
Amara Nasir, Anca Mazare, Xin Zhou, Shanshan Qin, Nikita Denisov, Lukas Zdrazil, Stepan Kment, Radek Zboril, Tariq Yasin, Patrik Schmuki
Summary: This study presents a low-cost, one-step photocatalytic method for synthesizing graphene oxide (GO) using commercial graphite and grey TiO2. GO formation is achieved through UV illumination of a slurry containing well-dispersed grey TiO2 and commercial graphite. The resulting GO-decorated TiO2 acts as a visible-light-active photocatalyst for applications such as pollutant degradation.
Review
Chemistry, Multidisciplinary
Maomao Xie, Meng Gao, Yang Yun, Martin Malmsten, Vincent M. M. Rotello, Radek Zboril, Omid Akhavan, Aliaksandr Kraskouski, John Amalraj, Xiaoming Cai, Jianmei Lu, Huizhen Zheng, Ruibin Li
Summary: Antimicrobial resistance (AMR) is a major threat to the environment and health, and antimicrobial nanomaterials are being explored as alternatives to conventional antibiotics. Some antimicrobial nanomaterials show AMR-independent antimicrobial effects, while others trigger the evolution of AMR. This review compares the mechanisms and relationships of antibiotics and antimicrobial nanomaterials, examines nano-microbe interactions, and provides an outlook on future antimicrobial nanomaterials.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Olivier Henrotte, Eva Yazmin Santiago, Artur Movsesyan, Luca Mascaretti, Morteza Afshar, Alessandro Minguzzi, Alberto Vertova, Zhiming M. Wang, Radek Zboril, Stepan Kment, Alexander O. Govorov, Alberto Naldoni
Summary: The investigation of photocatalytic systems at the nanoscale is crucial for understanding their fundamental principles, improving their design, and enhancing their applicability. A photochemical nanoscopy technique has been developed to detect the molecular products of plasmonic hot-carrier-driven photocatalytic reactions with nanometric precision. Applying this methodology to Au/TiO2 plasmonic photocatalysts, it was discovered that smaller and denser Au nanoparticle arrays have lower optical contribution but higher quantum efficiency in hot-hole-driven photocatalysis, which is closely related to population heterogeneity. This study also revealed the areas of oxidation and reduction product evolution in a single plasmonic nanodiode, demonstrating the bipolar behavior of such nanosystems. These findings enable quantitative investigations at the nanoscale to evaluate the photocatalytic reactivity of low-dimensional materials in various chemical reactions.
Review
Chemistry, Multidisciplinary
Iosif Tantis, Smita Talande, Vasileios Tzitzios, Georgia Basina, Vishal Shrivastav, Aristides Bakandritsos, Radek Zboril
Summary: This review focuses on recent advances in electrochemical energy storage (EES) technologies related to 2D crystals originating from non-layered 3D solids (non-van der Waals; nvdW) and their influence on the materials' features. The methods and challenges in top-down and bottom-up strategies towards nvdW 2D sheets and their applications in EES are discussed. Moreover, the opportunities and challenges of nvdW 2D systems in various applications are highlighted.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Tomas Malina, Cordula Hirsch, Alexandra Rippl, David Panacek, Katerina Polakova, Veronika Sedajova, Magdalena Scheibe, Radek Zboril, Peter Wick
Summary: Graphene oxide (GO) is a promising delivery nanoplatform, but its non-specific surface properties and heterogeneity in stability limit its commercial application. Evaluating the interaction of emerging graphene derivatives with endothelial and immune cells is important. The study demonstrated that graphene acid (GA) and cyanographene (GCN) have better biocompatibility and potential for drug/gene delivery compared to GO.
Review
Chemistry, Physical
En Zhao, Wenjun Zhang, Lin Dong, Radek Zboril, Zupeng Chen
Summary: Transfer hydrogenation using liquid hydrogen carriersas the direct proton sources under mild conditions has attracted considerable attention in the field of organic synthesis. Photocatalytic water-donating transfer hydrogenation (PWDTH) has emerged as an eco-friendly alternative to conventional hydrogenation technology. This paper discusses recent advances in PWDTH reactions, including the mechanism of hydrogen transfer and the design principles of efficient photocatalysts. It also explores the current challenges and future opportunities in this rapidly developing field.
Review
Chemistry, Multidisciplinary
Virender K. Sharma, Xingmao Ma, Radek Zboril
Summary: Water is a crucial component of the United Nations' sustainable development goals, and water reuse is becoming increasingly accepted in response to global water scarcity. However, traditional treatment processes face challenges in treating low concentrations of pollutants in the presence of other chemicals. Advanced oxidation processes and the use of single atom catalysts offer promising solutions to these challenges.
CHEMICAL SOCIETY REVIEWS
(2023)
Review
Chemistry, Multidisciplinary
Viterslav Hruby, Dagmar Zaoralova, Miroslav Medved, Aristeidis Bakandritsos, Radek Zboril, Michal Otyepka
Summary: Single-atom catalysts based on graphene derivatives are a promising class of materials with great potential in various fields. The rich chemistry of fluorographene allows for the synthesis of graphene derivatives with unique structural features, which lead to intriguing phenomena occurring between coordinated metals and the graphene backbone.
Article
Chemistry, Inorganic & Nuclear
Christina D. Polyzou, Patroula Gkolfi, Christos T. Chasapis, Vlasoula Bekiari, Ariadni Zianna, George Psomas, Malina Ondrej, Vassilis Tangoulis
Summary: In this study, aminated silica hybrid, spin-crossover nanoparticles (AmNPs) were proposed as potential drug nanocarriers. Drug release experiments at different pH values were conducted, and the interaction of the nanoparticles with calf-thymus DNA and serum albumins, as well as the corresponding binding constants, were investigated using various techniques.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Priti Sharma, Debdyuti Mukherjee, Sujoy Sarkar, Daniel Mandler, Rajender S. Varma, Manoj B. Gawande, Radek Zboril, Yoel Sasson
Summary: A straightforward and mild protocol for photochemical in situ selective hydrogenation was achieved using an Al-H2O system as a hydrogen donor and a Pd-g-C3N4 photocatalyst. This method showed excellent yield and selectivity for a wide range of olefins and nitro compounds (>99%) under visible light and ambient conditions. The Pd-g-C3N4 photocatalyst also demonstrated efficient bifunctional electrocatalytic activity for overall water splitting.
Article
Chemistry, Multidisciplinary
Michaela Polaskova, Ondrej Malina, Jiri Tucek, Petr Jakubec
Summary: The addition of Sc3+ ions into the ε-Fe2O3 crystal lattice increases the purity of the ε-Fe2O3 system and alters its magnetic and electrochemical properties.
Article
Chemistry, Multidisciplinary
Laetitia Bardet, Herve Roussel, Stefano Saroglia, Masoud Akbari, David Munoz-Rojas, Carmen Jimenez, Aurore Denneulin, Daniel Bellet
Summary: The thermal instability of silver nanowires leads to increased electrical resistance in AgNW networks. Understanding the relationship between structural and electrical properties of AgNW networks is crucial for their integration as transparent electrodes in flexible optoelectronics. In situ X-ray diffraction measurements were used to study the crystallographic evolution of Ag-specific Bragg peaks during thermal ramping, revealing differences in thermal and structural transitions between bare and SnO2-coated AgNW networks.
Article
Chemistry, Multidisciplinary
Nathalia Cancino-Fuentes, Arnau Manasanch, Joana Covelo, Alex Suarez-Perez, Enrique Fernandez, Stratis Matsoukis, Christoph Guger, Xavi Illa, Anton Guimera-Brunet, Maria V. Sanchez-Vives
Summary: This study provides a comprehensive characterization of graphene-based solution-gated field-effect transistors (gSGFETs) for brain recordings, highlighting their potential clinical applications.
Article
Chemistry, Multidisciplinary
Sikandar Aftab, Hailiang Liu, Dhanasekaran Vikraman, Sajjad Hussain, Jungwon Kang, Abdullah A. Al-Kahtani
Summary: This study examines the effects of hybrid nanoparticles made of NiO@rGO and NiO@CNT on the active layers of polymer solar cells and X-ray photodetectors. The findings show that these hybrid nanoparticles can enhance the charge carrier capacities and exciton dissociation properties of the active layers. Among the tested configurations, the NiO@CNT device demonstrates superior performance in converting sunlight into electricity, and achieves the best sensitivity for X-ray detection.
Article
Chemistry, Multidisciplinary
Hyo Jung Shin, Seung Gyu Choi, Fengrui Qu, Min-Hee Yi, Choong-Hyun Lee, Sang Ryong Kim, Hyeong-Geug Kim, Jaewon Beom, Yoonyoung Yi, Do Kyung Kim, Eun-Hye Joe, Hee-Jung Song, Yonghyun Kim, Dong Woon Kim
Summary: This study investigates the role of SOX9 in reactive astrocytes following ischemic brain damage using a PLGA nanoparticle plasmid delivery system. The results demonstrate that PLGA nanoparticles can reduce ischemia-induced neurological deficits and infarct volume, providing a potential opportunity for stroke treatment.
Article
Chemistry, Multidisciplinary
Anurag Chaudhury, Koushik Debnath, Nikhil R. Jana, Jaydeep K. Basu
Summary: The study investigates the interaction between nanoparticles and cell membranes, and identifies key parameters, including charge, crowding, and membrane fluidity, that determine the adsorbed concentration and unbinding transition of nanoparticles.
Article
Chemistry, Multidisciplinary
Sina Sadeghi, Fazel Bateni, Taekhoon Kim, Dae Yong Son, Jeffrey A. Bennett, Negin Orouji, Venkat S. Punati, Christine Stark, Teagan D. Cerra, Rami Awad, Fernando Delgado-Licona, Jinge Xu, Nikolai Mukhin, Hannah Dickerson, Kristofer G. Reyes, Milad Abolhasani
Summary: In this study, an autonomous approach for the development of lead-free metal halide perovskite nanocrystals is presented, which integrates a modular microfluidic platform with machine learning-assisted synthesis modeling. This approach enables rapid and optimized synthesis of copper-based lead-free nanocrystals.
Article
Chemistry, Multidisciplinary
Zahir Abbas, Nissar Hussain, Surender Kumar, Shaikh M. Mobin
Summary: The rational construction of free-standing and flexible electrodes for electrochemical energy storage devices is an emerging research focus. In this study, a redox-active metal-organic framework (MOF) was prepared on carbon nanofibers using an in situ approach, resulting in a flexible electrode with high redox-active behavior and unique properties such as high flexibility and lightweight. The prepared electrode showed excellent cyclic retention and rate capability in supercapacitor applications. Additionally, it could be used as a freestanding electrode in flexible devices at different bending angles.
Article
Chemistry, Multidisciplinary
Lishan Zhang, Xiaoting Zhang, Hui Ran, Ze Chen, Yicheng Ye, Jiamiao Jiang, Ziwei Hu, Miral Azechi, Fei Peng, Hao Tian, Zhili Xu, Yingfeng Tu
Summary: Photodynamic therapy (PDT) is a promising local treatment modality in cancer therapy, but its therapeutic efficacy is restricted by ineffective delivery of photosensitizers and tumor hypoxia. In this study, a phototactic Chlorella-based near-infrared (NIR) driven green affording-oxygen microrobot system was developed for enhanced PDT. The system exhibited desirable phototaxis and continuous oxygen generation, leading to the inhibition of tumor growth in mice. This study demonstrates the potential of using a light-driven green affording-oxygen microrobot to enhance photodynamic therapy.
Article
Chemistry, Multidisciplinary
Yujin Li, Jing Xu, Xinqi Luo, Futing Wang, Zhong Dong, Ke-Jing Huang, Chengjie Hu, Mengyi Hou, Ren Cai
Summary: In this study, hollow heterostructured materials were constructed using an innovative template-engaged method as cathodes for zinc-ion batteries. The materials exhibited fast Zn2+ transport channels, improved electrical conductivity, and controlled volume expansion during cycling. The designed structure allowed for an admirable reversible capacity and high coulombic efficiency.
Article
Chemistry, Multidisciplinary
Paritosh Mahato, Shashi Shekhar, Rahul Yadav, Saptarshi Mukherjee
Summary: This study comprehensively elucidates the role of the core and electrostatic surface of metal nanoclusters in catalytic reduction reactions. The electrostatic surface dramatically modulates the reactivity of metal nanoclusters.
Article
Chemistry, Multidisciplinary
Pei Liu, Mengdi Liang, Zhengwei Liu, Haiyu Long, Han Cheng, Jiahe Su, Zhongbiao Tan, Xuewen He, Min Sun, Xiangqian Li, Shuai He
Summary: This study demonstrates a simple and environmentally-friendly method for the synthesis of zinc oxide nanozymes (ZnO NZs) using wasted hop extract (WHE). The WHE-ZnO NZs exhibit exceptional peroxidase-like activity and serve as effective catalysts for the oxidation of 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2). In addition, a straightforward colorimetric technique for detecting both H2O2 and glucose was developed using the WHE-ZnO NZs as peroxidase-like catalysts.
Article
Chemistry, Multidisciplinary
Hyunkyu Oh, Young Jun Lee, Eun Ji Kim, Jinseok Park, Hee-Eun Kim, Hyunsoo Lee, Hyunjoo Lee, Bumjoon J. Kim
Summary: Mesoporous carbon particles have unique structural properties that make them suitable as support materials for catalytic applications. This study investigates the impact of channel nanostructures on the catalytic activity of porous carbon particles (PCPs) by fabricating PCPs with controlled channel exposure on the carbon surface. The results show that PCPs with highly open channel nanostructures exhibit significantly higher catalytic activity compared to those with closed channel nanostructures.
Article
Chemistry, Multidisciplinary
Yunjie Lu, Zhaohui Li, Zewei Li, Shihao Zhou, Ning Zhang, Jianming Zhang, Lu Zong
Summary: A tough, long-lasting adhesive and highly conductive nanocomposite hydrogel (PACPH) was fabricated via the synergy of interfacial entanglement and adhesion group densification. PACPH possesses excellent mechanical properties, interfacial adhesion strength, and conductivity, making it a promising material for long-term monitoring of human activities and electrocardiogram signals.
Article
Chemistry, Multidisciplinary
Zichao Wei, Audrey Vandergriff, Chung-Hao Liu, Maham Liaqat, Mu-Ping Nieh, Yu Lei, Jie He
Summary: We have developed a simple method to prepare polymer-grafted plasmonic metal nanoparticles with pH-responsive surface-enhanced Raman scattering. By using pH-responsive polymers as ligands, the aggregation of nanoparticles can be controlled, leading to enhanced SERS. The pH-responsive polymer-grafted nanoparticles show high reproducibility and sensitivity in solution, providing a novel approach for SERS without the need for sample pre-concentration.
Article
Chemistry, Multidisciplinary
Melis Ozge Alas Colak, Ahmet Gungor, Merve Buldu Akturk, Emre Erdem, Rukan Genc
Summary: This research investigates the effect of functionalizing carbon dots with hydroxyl polymers on their performance as electrode materials in a supercapacitor. The results show that the functionalized carbon dots exhibit excellent electrochemical performance and improved stability.