A facile one-step in situ synthesis of copper nanostructures/graphene oxide as an efficient electrocatalyst for 2-naphthol sensing application

A copper nanostructures-graphene oxide (Cu/GO) hybrid as a new electrocatalyst for highly sensitive detection of 2-naphthol (2-NAP) was successfully synthesized by a one-pot and in situ chemical reduction approach. The characterization results reveal that the cubic Cu nanostructures are tightly attached onto the GO sheets in the resulting hybrid. A lower oxidation potential and a larger peak current were observed for the 2-NAP oxidation at the Cu/GO modified electrode, demonstrating the synergistic electrocatalysis from Cu nanostructures and GO sheets. Consequently, the Cu/GO hybrid exhibits a low detection limit (5.0 nM) and wide linear ranges (0.1-4.0 mu M and 4.0-130.0 mu M) when used as a sensing material for the sensitive detection of 2-NAP. Finally, the fabricated sensor was successfully applied in the detection of 2-NAP in real samples and satisfactory recoveries in the range of 99.3%-104.0% were achieved. (C) 2014 Elsevier Ltd. All rights reserved.