Article
Chemistry, Analytical
Ali Firoozbakhtian, Morteza Hosseini, Mahsa Naghavi Sheikholeslami, Foad Salehnia, Guobao Xu, Hodjattallah Rabbani, Ebtesam Sobhanie
Summary: The rapid spread of SARS-CoV-2 has raised the need for efficient and rapid diagnostic tools. In this study, an electrochemiluminescence (ECL)-based detection system was developed and trained using machine learning algorithms to accurately diagnose COVID-19 with over 90% accuracy. The system provides a cost-effective and time-saving alternative to traditional testing methods.
ANALYTICAL CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Asma El Golli, Mosaab Echabaane, Cherif Dridi
Summary: A non-enzymatic amperometric glucose sensor based on Zinc Oxide (ZnO) and copper (Cu) composite membrane was designed. The Cu/ZnO nanocomposite was prepared using sol-gel technique and deposited on Glassy Carbon Electrode (GCE) for sensing electrode fabrication. The sensor exhibited favorable electrocatalytic properties for glucose oxidation in alkaline solution, with wide linear ranges, good sensitivity and selectivity, and fast response time.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Nanoscience & Nanotechnology
Nilem Khaliq, Muhammad Asim Rasheed, Maaz Khan, Muhammad Maqbool, Mashkoor Ahmad, Shafqat Karim, Amjad Nisar, Patrik Schmuki, Sung Oh Cho, Ghafar Ali
Summary: A hybrid nanostructure electrode based on Au/CdS QDs/TNTs was fabricated for nonenzymatic detection of cholesterol and hydrogen peroxide, showing enhanced sensitivity and selectivity. The biosensor demonstrated good reproducibility and thermal stability, with promising potential for enzyme-free biosensing applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Kun Wang, Yige Li, Manlin Qi, Chunyan Li, Biao Dong, Lin Xu, Lin Wang
Summary: A reliable copper oxide/carboxylated graphene quantum dots inverse opals array has been developed for non-enzymatic tracking of dopamine, and successfully detected the crucial quantity distribution of dopamine-related diseases in neuropathology and symptomatology.
Article
Chemistry, Analytical
Meijun Wan, Asha Jimu, Honglin Yang, Jingqiu Zhou, Xuemei Dai, Yunchao Zheng, Jing Ou, Yaxin Yang, Jing Liu, Lujun Wang
Summary: Using 3D-printing technology, a 3D-printed electrode (3DE) was fabricated using graphene/polylactic acid (PLA) filament. MXene quantum dots (MQDs) were then used to construct a novel sensor for highly sensitive detection of dopamine (DA). The sensor showed a low limit of detection (3 nM) and high selectivity for DA.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Jinyu Lin, Junchao Qian, Yaping Wang, Yue Yang, Yuxuan Zhang, Jianping Chen, Xingwang Chen, Zhigang Chen
Summary: The article introduces a novel and highly sensitive CeO2-Co3O4 QDs@porous carbon nanocomposite electrochemical sensor for detecting oxytetracycline in water samples. The experimental results show that the electrode exhibits excellent electrocatalytic performance and can effectively detect oxytetracycline.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Haiyu Li, Wan Wang, Zhijuan Wang, Qing Lv, Hua Bai, Qing Zhang
Summary: A paper-based colorimetric device for Hg2+ detection was developed using CdSe/ZnS quantum dots and TMB, achieving a low detection limit and accurate detection of real samples.
MICROCHEMICAL JOURNAL
(2021)
Article
Biochemical Research Methods
Duy Ba Ngo, Thanyarat Chaibun, Lee Su Yin, Benchaporn Lertanantawong, Werasak Surareungchai
Summary: This study aimed to develop a highly specific electrochemical DNA sensor using functionalized lead sulphide quantum dots for detecting hepatitis E virus genotype 3 DNA target, showing low detection and quantitation limits.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2021)
Article
Biophysics
Andreas Weltin, Jochen Kieninger, Gerald A. Urban, Sarah Buchholz, Susan Arndt, Nicole Rosskothen-Kuhl
Summary: This study developed an electrochemical method to turn the platinum stimulation microelectrodes of cochlear implants into electrochemical sensors. In vitro and in vivo experiments demonstrated the effectiveness and stability of this method. This research is significant for advancing implant functionality, long-term monitoring, and investigating electrode degradation in cochlear implant patients in situ.
BIOSENSORS & BIOELECTRONICS
(2022)
Article
Chemistry, Analytical
Wei Liu, Yunqi Wang, Fangfang Sheng, Bing Wan, Gangxu Tang, Shuxia Xu
Summary: In this paper, a nucleic acid dye-enhanced electrochemical biosensor based on a screen-printed carbon electrode modified with Au nanoparticles was developed for the detection of Hg2+ in water. The sensor showed simplicity, sensitivity, specificity, and good detection performance in actual environmental samples.
ANALYTICAL METHODS
(2022)
Article
Engineering, Environmental
A. T. Ezhil Vilian, Reddicherla Umapathi, Seung-Kyu Hwang, Yun Suk Huh, Young-Kyu Han
Summary: In this study, a reliable and selective electrochemical sensor consisting of Pd-Cu nanospheres supported on molybdenum carbide was prepared for the quick and accurate detection of NO2- in the aquatic environment. The sensor showed a low detection limit and high sensitivity, with a broad linear response range for NO2- detection. Additionally, the fabricated electrode demonstrated good recovery when applied to detecting nitrites in various samples such as sausages, river water, and milk.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Analytical
Kheibar Dashtian, Fatemeh Binabaji, Rouholah Zare-Dorabei
Summary: Wearable sweat sensors offer exciting opportunities for personal health monitoring and noninvasive biomarker measurements. This study presents a portable microfluidic device capable of simultaneous sweat sampling and fluorometric sensing of potential biomarkers for kidney disease monitoring. The device integrates seamlessly with smartphones for easy data retrieval and analysis. The sensors show exceptional performance, with low detection limits and remarkable selectivity. The evaluation extends to monitoring kidney diseases in real-world scenarios, showing the potential of low-cost, multidiagnostic microfluidic sensor arrays for enhanced disease detection and healthcare outcomes.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Liuyin Hu, Jiahua Cui, Yalin Wang, Jinping Jia
Summary: In this study, a sensitive electrochemical biosensor based on an enzyme-free and entropy-driven DNA walker is developed for the detection of Hg2+. The biosensor shows high selectivity and sensitivity, and performs well in real water samples.
ANALYTICAL METHODS
(2022)
Article
Chemistry, Physical
Manh Hoang Tran, Taehyun Park, Jaehyun Hur
Summary: By incorporating graphene quantum dots, the ZnO film's physical and chemical characteristics are improved, leading to enhanced transport of photogenerated carriers and longer charge lifetimes. Under appropriate GQD concentration, the ZnO:GQD/Poly-TPD photodiode shows balanced energy structure, increased mobility, and reduced charge recombination compared to other devices, demonstrating excellent performance in UV detection.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Analytical
Chandran Bhuvaneswari, Arumugam Elangovan, Narayanan Sudhan, Ganesan Vinodhkumar, Soorangkattan Saravanan, Venkataraman Balasubramanian, Chandrasekaran Sharmila, Sudha Karuppaiah
Summary: In this study, a novel electrochemical non-enzymatic chemo-sensor based on a low-cost hybrid graphene quantum dots/iron oxide/polypyrrole nanocomposite was synthesized and used for the determination of creatinine. The physicochemical properties of the prepared nanocomposite were studied, and it was found to exhibit excellent catalytic activity and high selectivity towards creatinine sensing.
MICROCHEMICAL JOURNAL
(2023)
Article
Agronomy
Gandura Omar Abagandura, Navreet Kaur Mahal, Nagender Pal Butail, Jashanjeet Kaur Dhaliwal, Asmita Gautam, Arun Bawa, Peter Kovacs, Sandeep Kumar
Summary: Manure application can increase soil carbon and nitrogen pools compared to mineral fertilizer application, especially at higher rates.
ARCHIVES OF AGRONOMY AND SOIL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Pratibha Tripathi, Rahul Uttam, Sandeep Kumar, Roman Dabrowski, Ravindra Dhar
Summary: This study examines the thermodynamic, dielectric, and electro-optical properties of a room temperature nematic liquid crystal mixed with surface-stabilized gold nanoparticles. The results show that the addition of nanoparticles decreases the transition temperature of the liquid crystal and enhances its dielectric anisotropy. The study also identifies a relaxation mode in the dielectric behavior, caused by the flip-flop motion of the nematic molecules.
Article
Telecommunications
Sandeep Kumar, Puspraj Singh Chauhan, Manpreet Kaur, Tarun Lata
Summary: This paper studies the effective capacity performance of a delay-sensitive communication system over a cascaded Rayleigh fading channel with arbitrary correlation. Closed-form mathematical expressions for the effective capacity are derived, and the effect of different fading parameters on the system's effective throughput is demonstrated.
WIRELESS PERSONAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Asmita Shah, Harish Singh, Pongthep Prajongtat, Manish Chandra Joshi, Supa Hannongbua, Nattaporn Chattham, Young-Ki Kim, Sandeep Kumar, Dharmendra Pratap Singh
Summary: Researchers have converted chestnut waste into reduced graphene oxide and nitrogen-doped reduced graphene oxide with pyridinic-N dominance. The synthesized catalyst exhibits excellent oxygen reduction reaction activity, surpassing that of the commercial Pt/C catalyst, and shows higher methanol tolerance.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
S. Vanishree Bhat, K. Swamynathan, V. A. Raghunathan, Sandeep Kumar
Summary: This report illustrates the importance of the oligo-ethyleneoxy side chain on the liquid crystallinity of steroidal mesogens. The ethyleneoxy benzoates of sterols exhibit cholesteric and polymorphic smectic mesophases, as well as frustrated phases such as TGB and blue phase. The mesogenic tendency of these molecules is analyzed based on the length of the ethyleneoxy side chain and the steroidal moiety, and their amphotropic behavior has been investigated using POM, DSC, SAXS, and SEM techniques.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Environmental Sciences
Namita Das, Himadri Rajput, Ashraf Aly Hassan, Sandeep Kumar
Summary: This study tested five widely employed coagulants for the treatment of complex oilfield-generated produced water. The results showed that ferric chloride was the most efficient coagulant, removing 74.25% of total solids, with a treatment cost of USD 4 per m(-3) of produced water.
Editorial Material
Pharmacology & Pharmacy
Ramesh Joga, Hitesh Kumar Behera, Chetan Dushant Sabanis, Simran Simran, Sandeep Kumar, Neeraj Kumar
Summary: Photoresponsive liposomes have the potential to become a non-invasive alternative to ELISA for detecting low levels of biomarkers. The US20210396744 patent application introduces novel liposomes that can detect target substances using light. However, ensuring stability and optimizing various parameters such as plasma stability and efficient loading of photosensitive components in the membrane will be crucial for the clinical success of this technology.
PHARMACEUTICAL PATENT ANALYST
(2023)
Article
Chemistry, Multidisciplinary
Vanishree S. Bhat, Marichandran Vadivel, Dharmendra Pratap Singh, V. A. Raghunathan, Arun Roy, Sandeep Kumar
Summary: In this study, a series of novel nitrogen and oxygen-incorporated chromenonaphthophenanthridine-based elliptical dimers were synthesized through tandem Pictet-Spengler cyclization followed by ipso-aromatic substitution in one-pot. Their mesophase characteristics were characterized by optical microscopy, differential scanning calorimetry, and X-ray diffraction studies. The photophysical properties were investigated using UV-vis and emission spectroscopy, and the charge transport properties were analyzed by time-of-flight measurements, with observed ambipolar mobilities of the order of 10(-3) cm(2) V-1 s(-1). These materials show promising potential for applications in organic electronics due to their high solubility, excellent thermal stability, self-organizing properties, and ambipolar charge transport characteristics.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Engineering, Electrical & Electronic
Dimpal Janu, Sandeep Kumar, Kuldeep Singh
Summary: GCN-CSS is a novel Graph Convolution Network-based cooperative spectrum sensing methodology that adapts to the dynamic changes in the Cognitive Radio Network. The proposed model is proven to be superior in different dynamic scenarios of the wireless environment through sufficient simulations.
IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY
(2023)
Article
Engineering, Electrical & Electronic
Khalid K. Almuzaini, Shalini Stalin, Sindhu P. Menon, Sandeep Kumar, Stephen Ojo, Prashant Kumar Shukla, Piyush Kumar Pareek, Piyush Kumar Shukla
Summary: In wireless sensor networks, the challenge lies in designing and managing the networks considering limited power, stringent bandwidth, dynamic topology, and high network density. The proposed IGRPSO protocol addresses these challenges by optimizing routing with minimal latency and a higher packet delivery ratio.
INTERNATIONAL JOURNAL OF COMMUNICATION SYSTEMS
(2023)
Review
Pharmacology & Pharmacy
Saurabh Shah, Ramesh Joga, Tejaswini Kolipaka, Chetan Sabnis Dushyantrao, Pooja Khairnar, Vivek Phatale, Giriraj Pandey, Saurabh Srivastava, Sandeep Kumar
Summary: This article introduces the liquid crystalline phase, which has attracted global attention due to its intriguing properties. It enumerates the different classes of liquid crystals and focuses on lyotropic liquid crystals (LLCs), which exhibit their liquid crystalline nature based on the surrounding solvent media. The article discusses the advantages of LLCs in drug delivery and tissue regeneration, fabrication techniques, and applications in novel therapeutic avenues.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2023)
Article
Chemistry, Multidisciplinary
T. Aravinda, Srilatha Rao, A. S. Sowmyashree, Ashwathanarayana Gowda, L. Parashuram, Kayim Pineda Urbina, Gururaj Kudur Jayaprakash, Sandeep Kumar
Summary: In this study, a metal-free phthalocyanine-based discotic liquid crystal (PcDLC) was tested for its corrosion inhibitory capacity on mild steel (MS) samples in 1.0 M HCl medium using potentiodynamic and electrochemical impedance parameters. The PcDLC exhibited excellent corrosion inhibition with a maximum efficiency of 89.61%. The strong adsorption of PcDLC onto the MS surface was responsible for this superior ability. Scanning electron microscopy and FTIR confirmed the formation of a protective layer of inhibitors on the MS surface. Density function theory revealed a strong interaction between the inhibitor and surface iron atoms.
Article
Information Science & Library Science
Sandeep Kumar, Tirthankar Ghosal, Asif Ekbal
Summary: Peer reviews are crucial in scientific communication, providing evaluation of research papers by multiple experts. This study proposes an unsupervised deep neural network approach for generating meta-reviews. Using a generic template, the method fills in the template with generated meta-review text to ensure consistency. This approach is beneficial for decision-making and helps in writing more informative meta-reviews.
INTERNATIONAL JOURNAL ON DIGITAL LIBRARIES
(2023)
Article
Geriatrics & Gerontology
Sagar Vyavahare, Sandeep Kumar, Kathryn Smith, Bharati Mendhe, Roger Zhong, Marion A. Cooley, Babak Baban, Carlos M. Isales, Mark Hamrick, William Hill, Sadanand Fulzele
Summary: Emerging evidence suggests that microRNA-141-3p plays a role in age-related pathologies. In this study, we inhibited miR-141-3p expression in aged mice and observed improved immune, bone, and muscle health. Treatment with Anti-miR-141-3p resulted in decreased pro-inflammatory cytokines, a shift from pro-inflammatory to anti-inflammatory immune cell populations, and improved bone microstructure and muscle fiber size. Molecular analysis revealed the role of miR-141-3p in regulating senescence and inflammation, as well as its potential crosstalk with FOXO-1 transcription factor. These findings suggest that inhibiting miR-141-3p may be a potential strategy for promoting healthy aging.
Article
Geriatrics & Gerontology
Mohini Gharpure, Jie Chen, Resheek Nerella, Sagar Vyavahare, Sandeep Kumar, Carlos M. Isales, Mark Hamrick, Satish Adusumilli, Sadanand Fulzele
Summary: Sarcopenia, a condition characterized by decreased muscle mass, altered muscle composition, and reduced muscle strength, disproportionately affects males and females with age. This study identified differentially regulated genes in aged skeletal muscle from males and females, with 269 genes showing at least a twofold expression difference. Gene Ontology analysis revealed distinct pathways involved in aged female and male skeletal muscle, suggesting the potential for sex-specific therapeutic targets to combat sarcopenia and promote healthy aging.
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)