Journal
ELECTROCHIMICA ACTA
Volume 169, Issue -, Pages 103-108Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.04.073
Keywords
CdS QD sensitized B/N co-doped TiO2 solar cell; B/N co-doped TiO2; NiS counter electrode; ((CH3)(4)N)(2)S/((CH3)(4)N)(2)S-n electrolyte
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The highly crystalline mesoporous B/N co-doped TiO2 nanomaterial is successfully synthetized using a facile process. A modified polysulfide redox couple, (CH3)(4)N)(2)S/((CH3)(4)N)(2)Sn, was employed in CdS quantum dots (QDs) sensitized B/N co-doped TiO2 solar cell with ZnS passivation layers and NiS as counter electrode, followed by chemical bath deposition (CBD) in an organic solution to prepare the QDs-cell to ensure high wettability and superior penetration ability of the B/N co-doped TiO2 films, then obtained an open-circuit photovoltage of 1.23 V, a high ff of 89%, a short-circuit photocurrent (J(sc)) of 4.46 mA cm (2), and yielding a high overall energy conversion of 4.88%. (C) 2015 Elsevier Ltd. All rights reserved.
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