4.2 Article Proceedings Paper

Novel naphthylpyridines from cobalt-catalyzed cyclotrimerization of a chiral diyne

Journal

MONATSHEFTE FUR CHEMIE
Volume 149, Issue 4, Pages 755-763

Publisher

SPRINGER WIEN
DOI: 10.1007/s00706-017-2083-9

Keywords

Biaryls; Cycloadditions; Catalysis; Heterocycles; Alkynes

Funding

  1. Johannes Kepler University Linz
  2. LIKAT
  3. Leibniz-Gemeinschaft

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The concise synthesis of a novel chiral diyne substrate for the assembly of chiral naphthylpyridines was described and different conditions for the cobalt-catalyzed co-cyclotrimerization with nitriles investigated. The products are novel naphthylpyridines possessing configurationally stable biaryl axes. [GRAPHICS] .

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