4.6 Article

Cerium-doped porous K-birnessite manganese oxides microspheres as pseudocapacitor electrode material with improved electrochemical capacitance

Journal

ELECTROCHIMICA ACTA
Volume 182, Issue -, Pages 1070-1077

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.10.028

Keywords

Manganese oxides; Cerium; Doping; Supercapacitor; Porosity

Funding

  1. Natural Science Foundation of Hebei Province [B2012203069, B2012203070]
  2. education department of Hebei province on natural science research key projects for institution of higher learning [ZH2011228]

Ask authors/readers for more resources

Cerium-doped nanosheet-based porous delta-MnO2 microspheres have been successfully prepared via a simple hydrothermal process. Electrochemical measurements showed that appropriate amount of cerium doping can significantly increase the speicific capacitance of delta-MnO2. It is found that 1.5% cerium-doped manganese oxides exhibit the best specific capacitance of 382.38 F g(-1) at a current density of 1 A g(-1). In terms of ion transport kinetics, cerium doping can shorten the diffusion path length and increase the ion transfer rate by changing the partical size, porosity density and conductivity of manganese oxides materials. (C) 2015 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Computer Science, Artificial Intelligence

Alleviating pseudo-touching in attention U-Net-based binarization approach for the historical Tibetan document images

Penghai Zhao, Weilan Wang, Guowei Zhang, Yuqi Lu

Summary: This study focuses on the binarization problem in degraded historical Tibetan document images and proposes an improved approach. By rescaling the input and output of the attention U-Net and accelerating the construction of the training set, the issue of pseudo-touching is successfully addressed, leading to better performance across several metrics.

NEURAL COMPUTING & APPLICATIONS (2023)

Review Genetics & Heredity

Penetrance of MYOC gene mutation in primary open-angle glaucoma: A systematic review and meta-analysis

Juan-Juan Xie, Guo-Wei Zhang, Hai-Yue Cui, Na Li, Xing-Xing Liu, Meng-Yao Hao, Shao-Wen Wang, Hong Lu

Summary: The penetrance of MYOC gene mutation in primary open-angle glaucoma (POAG) shows significant differences due to different mutation sites. Age and ethnic differences are important factors affecting the penetrance of MYOC mutation.

OPHTHALMIC GENETICS (2022)

Article Hematology

Characteristics of the Thrombus Formation in Transgenic Mice with Platelet-Targeted Factor VIII Expression

Yun Wang, Jianhua Mao, Li Li, Bing Xiao, Zheng Ruan, Yichen Liu, Guowei Zhang, Dawei Wang, Jian-Qing Mi, Chao Fang, Xiaodong Xi, Xiaofeng Shi, Jin Wang

Summary: Platelet-targeted FVIII gene therapy can efficiently recover the bleeding phenotype in patients with hemophilia A, while the ectopic expression of FVIII in platelets shows varying effects on thrombus formation under physiological and pathological conditions. Specific morphological features of thrombi may contribute to the efficacy and safety of platelet-targeted FVIII gene therapy for HA.

THROMBOSIS AND HAEMOSTASIS (2022)

Article Ophthalmology

Identification and Integrated Analysis of the miRNA-mRNA Regulatory Network in Lens from an H2O2-Induced Zebrafish Cataract Model

Mu Zhang, Jiawei Luo, Xiaoqing Chen, Yanhua Chen, Pengfei Li, Guowei Zhang, Huaijin Guan, Peirong Lu

Summary: The regulatory mechanisms of age-related cataract (ARC) formation were explored and a miRNA-mRNA regulatory network related to the DNA repair process in a zebrafish cataract model was constructed. These findings have important implications for the treatment of ARC.

CURRENT EYE RESEARCH (2022)

Article Management

Robust drone selective routing in humanitarian transportation network assessment

Guowei Zhang, Ning Jia, Ning Zhu, Yossiri Adulyasak, Shoufeng Ma

Summary: Assessing a humanitarian transportation network early after a disaster is crucial for reducing casualties. Drones are considered for the assessment operations due to their potential. However, a novel challenge arises in the drone arc routing problem where drones can travel off the road network. To address this challenge, a graph transformation technique and a robust team orienteering problem with uncertain assessment time are proposed. The problem is solved efficiently using path-based reformulation and Lagrangian decomposition, and an exact branch-and-price framework is applied.

EUROPEAN JOURNAL OF OPERATIONAL RESEARCH (2023)

Letter Surgery

The Hand as Foot teaching method in several conventional end-to-side shunt procedures for portal hypertension

Guowei Zhang, Rui Liu, Wanxiang Wang, Fan Yang

ASIAN JOURNAL OF SURGERY (2022)

Article Integrative & Complementary Medicine

Exploring the Protective Effects and Mechanism of Huaji Jianpi Decoction against Nonalcoholic Fatty Liver Disease by Network Pharmacology and Experimental Validation

Hongkun Xue, Yu Wang, Hongwei Xiang, Qi Song, Guowei Zhang, Jianguo Wang, Shaoqin Ge

Summary: This paper aimed to predict the mechanisms of Huaji Jianpi Decoction (HJJPD) against nonalcoholic fatty liver disease (NAFLD) using network pharmacology combined with animal experiments. The study identified candidate compounds and corresponding genes from HJJPD that are associated with activity against NAFLD, and constructed network of them. Inflammatory response and lipid metabolism-related signaling pathways were found to be critical pathways mediating the therapeutic effect of HJJPD. Experimental validation showed that HJJPD can inhibit hepatic steatosis and decrease mRNA expression levels. The study suggests that HJJPD exerts its effect on NAFLD through multitargets, multicompounds, and multipathways, and the network pharmacology-based approach provides insights for understanding the interrelationship between complex diseases and interventions of HJJPD.

EVIDENCE-BASED COMPLEMENTARY AND ALTERNATIVE MEDICINE (2022)

Article Materials Science, Multidisciplinary

Tribological performances of CuSn10Bi3 alloy containing MoSi2 and ferrophosphorus under starved lubrication

Dongya Yang, Jiajun Li, Gengrui Zhao, Honggang Wang, Zhenyu Li, Shengsheng Chen, Gui Gao, Guowei Zhang, Hong Xu

Summary: This study investigated the effects of molybdenum disilicide and ferrophosphorus particles on the tribological properties of copper-tin bismuth bimetallic bearing materials. The addition of these particles was found to improve the mechanical and wear resistance properties of the alloys.

MATERIALS SCIENCE AND TECHNOLOGY (2023)

Article Chemistry, Physical

Improved microstructure and shear strength of the Al/steel bimetal prepared by compound casting under magnetic field

Huan Yu, Guowei Zhang, Weize Lv, Hong Xu, Changjun Xu

Summary: An Al-7Si-Cu-Mg-Mn/steel bimetal was prepared by compound casting, and the effect of a coupled traveling and rotating magnetic field on the interface microstructure and shear strength was investigated. The magnetic field resulted in changes in the interface layer thickness, element concentration gradient, and dissolution rate of intermetallic compounds, leading to an increase in shear strength.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Age hardening of Al-7Si-0.5Mg alloy: Role of Si size and distribution

Guowei Zhang, Zhaojie Wang, Changjun Xu, Hong Xu, Cong Wang

Summary: The age-hardening behavior of the Al-7Si-0.5Mg alloy was studied with different sizes and distributions of Si phase. The specimen with fine and homogeneous Si exhibited accelerated age-hardening kinetics and higher hardness compared to the specimen with coarse and clustered Si, attributed to the higher dislocation density caused by thermal contraction mismatch. The overlapping of the plastically-affected zone of adjacent Si in the specimen with large and clustered Si resulted in reduced volume fraction of the plastically-affected zone, lower dislocation density, and slower age-hardening kinetics. The relationship between Si radius and critical inter-particle spacing for minimizing interaction and maximizing dislocation density and age-hardening kinetics was established.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Engineering, Multidisciplinary

A HEURISTICALLY ACCELERATED REINFORCEMENT LEARNING METHOD FOR MAINTENANCE POLICY OF AN ASSEMBLY LINE

Xiao Wang, Guowei Zhang, Yongqiang Li, Na Qu

Summary: This paper investigates the maintenance policy for a 2M1B assembly line system. By using an SMDP model and the HAMRL method, the learning process is accelerated and the maintenance strategy for the system is obtained. Empirical results show that the HAMRL algorithm has advantages in larger space and practical problems.

JOURNAL OF INDUSTRIAL AND MANAGEMENT OPTIMIZATION (2023)

Article Engineering, Marine

Research on Structural Response Characteristics of Trapezoidal Floating Body in Waves

Xuemin Song, Weiqin Liu, Guowei Zhang

Summary: This paper presents a study on the structural response of a trapezoidal floating body in waves through model testing and numerical simulation. The results conclude that the numerical method is effective in predicting the structural response characteristics of a trapezoidal floating body.

JOURNAL OF MARINE SCIENCE AND ENGINEERING (2022)

Article Ophthalmology

miR-125a-3p regulates apoptosis by suppressing TMBIM4 in lens epithelial cells

Lihua Kang, Jiawei Luo, Pengfei Li, Guowei Zhang, Miao Wei, Min Ji, Huaijin Guan

Summary: This study discovered that miR-125a-3p regulates apoptosis in LECs by suppressing TMBIM4, offering a new therapeutic target for cataract.

INTERNATIONAL OPHTHALMOLOGY (2023)

Proceedings Paper Computer Science, Hardware & Architecture

A Scalable Architecture for Reprioritizing Ordered Parallelism

Gilead Posluns, Yan Zhu, Guowei Zhang, Mark C. Jeffrey

Summary: Hive is a task-based execution model and multicore architecture that extracts abundant fine-grain parallelism from algorithms with priority updates, while retaining their strict priority schedules. By directly supporting updates in the interface, identifying the novel scheduler-carried dependence, and speculating on such dependences with task versioning, Hive enables safe speculative updates to the schedule and improves performance significantly.

PROCEEDINGS OF THE 2022 THE 49TH ANNUAL INTERNATIONAL SYMPOSIUM ON COMPUTER ARCHITECTURE (ISCA '22) (2022)

Article Electrochemistry

Recent advances in Bio-mass by electrochemically strategies generated hydrogen gas production: Environmentally sustainable technologies innovation

Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro

Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

ACGNet: An interpretable attention crystal graph neural network for accurate oxidation potential prediction

Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao

Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Enhanced electrochemical performance of CuO/NiO/rGO for oxygen evolution reaction

P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha

Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Carbon nanofibers implanted porous catalytic metal oxide design as efficient bifunctional electrode host material for lithium-sulfur battery

Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li

Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Spray coating of carbon nanoparticles as an effective and scalable method to enhance the performance of stainless steel anode in microbial electrochemical systems

Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo

Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical properties of Li-rich ternary cathode material Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase

Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu

Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Post-mortem analysis of the Li-ion battery with charge/discharge deterioration in high- and low-temperature environments

Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda

Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A Co3O4-x/Co nanocomposite with synergistically enhanced electrochemical activity for reduction of nitrite to ammonia

Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen

Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Facile fabrication of NaOH nanorods on pencil graphite electrode for simultaneous electrochemical detection of natural antioxidants by deep eutectic solvent

Berna Dalkiran, Havva Bekirog

Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A three-dimensional fibrous tungsten-oxide/carbon composite derived from natural cellulose substance as an anodic material for lithium-ion batteries

Sijun Ren, Jianguo Huang

Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Stabilizing the dissolution kinetics by interstitial Zn cations in CoMoO4 for oxygen evolution reaction at high potential

Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian

Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Molecular insights on optimizing nanoporous carbon-based supercapacitors with various electrolytes

Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings

Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Interaction between bilirubin oxidase and Au nanoparticles distributed over dimpled titanium foil towards oxygen reduction reaction

Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou

Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical supercapacitor and water splitting electrocatalysis applications of self-grown amorphous Ni(OH)2 nanosponge-balls

Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane

Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Versatile mixed ionic-electronic conducting binders for high-power, high-energy batteries

Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado

Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.

ELECTROCHIMICA ACTA (2024)