4.6 Article

Electroactive self-assembled monolayers: A versatile function to fit symmetric voltammetric peak

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 51, Issue -, Pages 137-143

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2014.12.023

Keywords

Self-assembled monolayers; Cyclic voltammetry; Lateral interactions; Generalized Gaussian function

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We propose a versatile function to fit adsorption voltammetric peak in order to extract the characteristic parameters such as the full width at half maximum, the peak potential, the peak current and the surface coverage. Based on the generalized Gaussian function and supported by generalized lateral interaction model, this method has been tested on different electroactive self-assembled monolayers (i.e. ferrocene, bithiophene, tetrathiafulvalene and radical aminoxyl units). (C) 2014 Elsevier B.V. All rights reserved.

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