Journal
ELECTROANALYSIS
Volume 28, Issue 2, Pages 296-303Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201500308
Keywords
Chemically modified electrode; Square wave anodic stripping voltammetry; Simultaneous determination; Cu(II) and Cd(II) determination
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A chemically modified electrode was constructed for rapid, simple, accurate, selective and highly sensitive simultaneous determination of Cu(II) and Cd(II) using square wave anodic stripping voltammetry. The electrode was prepared by incorporation of SiO2 nanoparticles, coated with a newly synthesized Schiff base, in carbon paste electrode. The limit of detection was found to be 0.28 ngmL(-1) and 0.54 ngmL(-1) for Cu(II) and Cd(II), respectively. The proposed chemically modified electrode was used for the determination of copper and cadmium in several foodstuffs and water samples.
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