Journal
MICROCHIMICA ACTA
Volume 184, Issue 6, Pages 1659-1667Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-017-2159-6
Keywords
QTF; Resonance sensor; Vapor sensor; Polystyrene; VOC; Hand-held prototype; Polymer sensors; Microwire sensors
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Funding
- DIAT-DRDO project
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The authors describe a sensor capable of detecting methanol adulteration of ethanol. The sensor is based on the use of quartz tuning forks (QTFs) that were functionalized with polymer wires made from a combination of polystyrene (PS) and aniline. Exposure to organic vapors causes the resonance frequency of the functionalized QTF to change, and this can be used to identify the type and concentration of the analyte. A mixture of methanol and ethanol vapors in varying concentrations was exposed to the QTF polymer system. The resulting shift in the resonance frequency of the QTF was firstly used to determine the concentration of alcohol vapor, which is reflected in the amount of shift. Secondly, the nature of change in resonance frequency was used to determine the type of alcohol exposed to the sensor. The sensitivity and selectivity of the sensors to ethanol and methanol vapors has been investigated. A portable hand-held prototype sensor has been developed which displays the percentage of two alcohols it is exposed to. It can detect ethanol adulteration where the methanol concentration is as low as 5%.
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