4.2 Article

Synthesis of sarcodictyin A analogue containing 14-methyl group and C(12)=C(13) bond in ring A from levoglucosenone

Journal

MENDELEEV COMMUNICATIONS
Volume 27, Issue 2, Pages 119-121

Publisher

ELSEVIER
DOI: 10.1016/j.mencom.2017.03.003

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Funding

  1. Russian Foundation for Basic Research [14-03-97007-p_povolzh'e a]
  2. President of the Russian Federation [SP-1934.2015.4]

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Starting from levoglucosenone piperilene Diels-Alder adduct a total synthesis of sarcodictyin A analogue containing 14-methyl group and C(12)=C(13) bond in ring A was performed, where the key step was the intramolecular cyclization between acetylene and aldehyde moieties to produce a 10-membered carbocycle.

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