Journal
MACROMOLECULES
Volume 50, Issue 20, Pages 7984-7992Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.7b01738
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Funding
- NSFC [21404031, U1204212]
- Henan Provience [2016GGJS-021]
- Henan University [yqpy20140058]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province [C20150011]
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Molecular electronic structure plays a vital role in the photovoltaic performances in polymer solar cells (PSCs) due to their influences on light-harvesting, charge carrier transfer, pi-pi stacking, etc. Indacenodithiophene as a star unit has been well studied in PSCs; various structural derivation methods have been tried, but they are still not efficient in improvement of power conversion efficiencies (PCE) due to the narrow optical absorptions. In this contribution, a novel planar DMIDT with extended lateral pi-electron delocalization is efficiently synthesized via introduction of sp(2) hybrid carbons as the bridge atoms. Based on this novel building block, a two-dimensional conjugated polymer PDMIDT-TPD is prepared, and the unique structure improves the conjugation at the lateral direction, enlarges the electron delocalization area, and greatly broadens the absorption spectrum with a full coverage from 350 to 700 nm. Finally, a PCE of 8.26% is achieved when blended with PC71BM, which is the highest result among the IDT-based polymer donors. Meanwhile, PDMIDT-TPD also presents good compatibility with the non-fullerene acceptor, and a preliminary PCE of 6.88% is obtained. In all, this work not only provides an excellent donor material but also offers a general and simple derivation strategy for fused aromatic building blocks.
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