Journal
MACROMOLECULES
Volume 50, Issue 20, Pages 7895-7900Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.7b01130
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Funding
- MEXT [15H05799]
- Grants-in-Aid for Scientific Research [15H05796, 15H05799] Funding Source: KAKEN
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For the copolymerization of cyclohexene oxide (CHO) with phthalic anhydride (PA), cationic complex [Co(III)(dmap)(2)-Salphen] [BF4] (3) showed higher activity than a combination of Co-Salphen-Cl (2) with 1 equiv of DMAP. The catalytic activity was further improved by using a bimetallic complex 5 in which the Co(III)(dmap)(2)- Salphen moiety was bridged by a 1,2,5,6-substituted naphthalene linker. A similar trend of catalytic activity was detected for the copolymerization, of CHO with CO2.
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