Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 38, Issue 7, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201600746
Keywords
freeze drying; hydrogels; polymer processing; shape memory polymers
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Funding
- National Natural Science Foundation of China [21504077]
- State Key Laboratory of Chemical Engineering [SKL-ChE-14D04, SKL-ChE-15T]
- Natural Science Foundation of Zhejiang Province [LQ15B060002]
- Program-oriented funding Helmholtz Association
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Device applications of shape memory polymers demand diverse shape changing geometries, which are currently limited to non-omnidirectional movement. This restriction originates from traditional thermomechanical programming methods such as uniaxial, biaxial stretching, bending, or compression. A solvent-modulated programming method is reported to achieve an omnidirectional shape memory behavior. The method utilizes freeze drying of hydrogels of polyethylene glycol networks with a melting transition temperature around 50 degrees C in their dry state. Such a process creates temporarily fixed macroporosity, which collapses upon heating, leading to significant omnidirectional shrinkage. These shrunken materials can swell in water to form hydrogels again and the omnidirectional programming and recovery can be repeated. The fixity ratio (R-f) and recovery ratio (R-r) can be maintained at 90% and 98% respectively upon shape memory multicycling. The maximum linear recoverable strain, as limited by the maximum swelling, is approximate to 90%. Amongst various application potentials, one can envision the fabrication of multiphase composites by taking advantages of the omnidirectional shrinkage from a porous polymer to a denser structure.
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